{"title":"Potassium Benzoate-Doped PEDOT:PSS for Improving the Open-Circuit Voltage and Power Conversion Efficiency of Inverted Perovskite Solar Cells","authors":"Nian Liu, Guanglei Cui, Xianhu Wu, Gaojie Xia, Jieyu Bi, Jilong Sun, Min Gu","doi":"10.1002/solr.202400780","DOIUrl":null,"url":null,"abstract":"<p>Inverted perovskite solar cells (IPSCs) have become a research hotspot in the field of photovoltaics due to their excellent photovoltaic performance, minimal hysteresis, and low fabrication costs. Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS), as an inexpensive hole transport material, has been widely applied in IPSCs. However, PEDOT:PSS has drawbacks such as energy-level mismatch with perovskite, severe interfacial defects, low hole transport rate, and low conductivity. Therefore, modifying and improving PEDOT:PSS is of practical value. Herein, potassium benzoate is introduced to dope PEDOT:PSS, enhancing its conductivity and accelerating hole transport in the device, making the energy levels between PEDOT:PSS and perovskite more compatible. More importantly, potassium benzoate-doped PEDOT promotes crystal growth, increases the grain size of the perovskite film, and passivates interfacial defects. The open-circuit voltage (<i>V</i><sub>oc</sub>) of the device increases from 1.107 to 1.137 V, and the power conversion efficiency improves from the original 17.24% to 20.15%. This study provides a new approach to develop inverted PSCs.</p>","PeriodicalId":230,"journal":{"name":"Solar RRL","volume":"9 5","pages":""},"PeriodicalIF":6.0000,"publicationDate":"2025-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solar RRL","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/solr.202400780","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
Abstract
Inverted perovskite solar cells (IPSCs) have become a research hotspot in the field of photovoltaics due to their excellent photovoltaic performance, minimal hysteresis, and low fabrication costs. Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS), as an inexpensive hole transport material, has been widely applied in IPSCs. However, PEDOT:PSS has drawbacks such as energy-level mismatch with perovskite, severe interfacial defects, low hole transport rate, and low conductivity. Therefore, modifying and improving PEDOT:PSS is of practical value. Herein, potassium benzoate is introduced to dope PEDOT:PSS, enhancing its conductivity and accelerating hole transport in the device, making the energy levels between PEDOT:PSS and perovskite more compatible. More importantly, potassium benzoate-doped PEDOT promotes crystal growth, increases the grain size of the perovskite film, and passivates interfacial defects. The open-circuit voltage (Voc) of the device increases from 1.107 to 1.137 V, and the power conversion efficiency improves from the original 17.24% to 20.15%. This study provides a new approach to develop inverted PSCs.
Solar RRLPhysics and Astronomy-Atomic and Molecular Physics, and Optics
CiteScore
12.10
自引率
6.30%
发文量
460
期刊介绍:
Solar RRL, formerly known as Rapid Research Letters, has evolved to embrace a broader and more encompassing format. We publish Research Articles and Reviews covering all facets of solar energy conversion. This includes, but is not limited to, photovoltaics and solar cells (both established and emerging systems), as well as the development, characterization, and optimization of materials and devices. Additionally, we cover topics such as photovoltaic modules and systems, their installation and deployment, photocatalysis, solar fuels, photothermal and photoelectrochemical solar energy conversion, energy distribution, grid issues, and other relevant aspects. Join us in exploring the latest advancements in solar energy conversion research.