Potassium Benzoate-Doped PEDOT:PSS for Improving the Open-Circuit Voltage and Power Conversion Efficiency of Inverted Perovskite Solar Cells

IF 6 3区 工程技术 Q2 ENERGY & FUELS
Solar RRL Pub Date : 2025-01-15 DOI:10.1002/solr.202400780
Nian Liu, Guanglei Cui, Xianhu Wu, Gaojie Xia, Jieyu Bi, Jilong Sun, Min Gu
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Abstract

Inverted perovskite solar cells (IPSCs) have become a research hotspot in the field of photovoltaics due to their excellent photovoltaic performance, minimal hysteresis, and low fabrication costs. Poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS), as an inexpensive hole transport material, has been widely applied in IPSCs. However, PEDOT:PSS has drawbacks such as energy-level mismatch with perovskite, severe interfacial defects, low hole transport rate, and low conductivity. Therefore, modifying and improving PEDOT:PSS is of practical value. Herein, potassium benzoate is introduced to dope PEDOT:PSS, enhancing its conductivity and accelerating hole transport in the device, making the energy levels between PEDOT:PSS and perovskite more compatible. More importantly, potassium benzoate-doped PEDOT promotes crystal growth, increases the grain size of the perovskite film, and passivates interfacial defects. The open-circuit voltage (Voc) of the device increases from 1.107 to 1.137 V, and the power conversion efficiency improves from the original 17.24% to 20.15%. This study provides a new approach to develop inverted PSCs.

Abstract Image

苯甲酸钾掺杂PEDOT:PSS提高倒置钙钛矿太阳能电池开路电压和功率转换效率
倒置钙钛矿太阳能电池(IPSCs)因其优异的光伏性能、最小的滞后和较低的制造成本而成为光伏领域的研究热点。聚(3,4-乙烯二氧噻吩):聚(苯乙烯磺酸盐)(PEDOT:PSS)作为一种廉价的空穴传输材料,在ipsc中得到了广泛的应用。然而,PEDOT:PSS存在与钙钛矿的能级不匹配、严重的界面缺陷、低空穴输运率和低电导率等缺点。因此,对PEDOT:PSS进行改进和改进具有实用价值。本文引入苯甲酸钾掺杂PEDOT:PSS,增强PEDOT:PSS的电导率,加速器件中的空穴输运,使PEDOT:PSS与钙钛矿之间的能级更加相容。更重要的是,苯甲酸钾掺杂PEDOT促进了晶体的生长,增加了钙钛矿膜的晶粒尺寸,钝化了界面缺陷。器件的开路电压Voc由1.107 V提高到1.137 V,功率转换效率由原来的17.24%提高到20.15%。本研究为倒置PSCs的制备提供了新的途径。
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来源期刊
Solar RRL
Solar RRL Physics and Astronomy-Atomic and Molecular Physics, and Optics
CiteScore
12.10
自引率
6.30%
发文量
460
期刊介绍: Solar RRL, formerly known as Rapid Research Letters, has evolved to embrace a broader and more encompassing format. We publish Research Articles and Reviews covering all facets of solar energy conversion. This includes, but is not limited to, photovoltaics and solar cells (both established and emerging systems), as well as the development, characterization, and optimization of materials and devices. Additionally, we cover topics such as photovoltaic modules and systems, their installation and deployment, photocatalysis, solar fuels, photothermal and photoelectrochemical solar energy conversion, energy distribution, grid issues, and other relevant aspects. Join us in exploring the latest advancements in solar energy conversion research.
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