{"title":"Rapid growth kinetics of β-Fe3Ge2 intermetallic compound within undercooled liquid Fe–Ge alloys","authors":"N. S. Hou, D. L. Geng, G. Y. Zhu, B. Wei","doi":"10.1063/5.0253749","DOIUrl":null,"url":null,"abstract":"The rapid dendrite growth of the β-Fe3Ge2 intermetallic compound within two liquid Fe–Ge alloys was investigated using the bulk undercooling technique. The liquid undercooling was achieved up to 202 K (0.14TL) and 227 K (0.16TL) for hypereutectic Fe70Ge30 and Fe67Ge33 alloys, respectively, where the primary β-Fe3Ge2 phase always exhibited non-faceted growth characteristics. Within the Fe70Ge30 alloy, the β-Fe3Ge2 phase morphology transformed from columnar to equiaxed dendrites with increasing undercooling, where the maximum growth velocity was measured as 1.44 m/s at 141 K undercooling. Beyond this undercooling threshold, the (β-Fe3Ge2 + α1-Fe17Ge3) anomalous eutectic grew directly from the undercooled liquid, which may be attributed to the remarkably enhanced nucleation rate of the α1-Fe17Ge3 phase. For the Fe67Ge33 alloy, the primary β-Fe3Ge2 dendrites achieved a high growth velocity of 3.53 m/s at the maximum 227 K undercooling. Furthermore, the Vickers hardness of the β-Fe3Ge2 compound in these two alloys was improved significantly, which resulted mainly from microstructure refinement.","PeriodicalId":8094,"journal":{"name":"Applied Physics Letters","volume":"14 1","pages":""},"PeriodicalIF":3.5000,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Physics Letters","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.1063/5.0253749","RegionNum":2,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"PHYSICS, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
The rapid dendrite growth of the β-Fe3Ge2 intermetallic compound within two liquid Fe–Ge alloys was investigated using the bulk undercooling technique. The liquid undercooling was achieved up to 202 K (0.14TL) and 227 K (0.16TL) for hypereutectic Fe70Ge30 and Fe67Ge33 alloys, respectively, where the primary β-Fe3Ge2 phase always exhibited non-faceted growth characteristics. Within the Fe70Ge30 alloy, the β-Fe3Ge2 phase morphology transformed from columnar to equiaxed dendrites with increasing undercooling, where the maximum growth velocity was measured as 1.44 m/s at 141 K undercooling. Beyond this undercooling threshold, the (β-Fe3Ge2 + α1-Fe17Ge3) anomalous eutectic grew directly from the undercooled liquid, which may be attributed to the remarkably enhanced nucleation rate of the α1-Fe17Ge3 phase. For the Fe67Ge33 alloy, the primary β-Fe3Ge2 dendrites achieved a high growth velocity of 3.53 m/s at the maximum 227 K undercooling. Furthermore, the Vickers hardness of the β-Fe3Ge2 compound in these two alloys was improved significantly, which resulted mainly from microstructure refinement.
期刊介绍:
Applied Physics Letters (APL) features concise, up-to-date reports on significant new findings in applied physics. Emphasizing rapid dissemination of key data and new physical insights, APL offers prompt publication of new experimental and theoretical papers reporting applications of physics phenomena to all branches of science, engineering, and modern technology.
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