A. S. Kubasov, A. V. Golubev, O. M. Stepanova, K. Yu. Zhizhin, N. T. Kuznetsov
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引用次数: 0
Abstract
This paper presents the synthesis of sulfonium derivatives of the closo-decaborate anion with exo-polyhedral carbonyl groups [B10H9S(CH2C(=O)R)2]– (R = Me, Ph, p-C6H4Cl, Nh). The composition and structure have been confirmed by elemental analysis, 11B, 1H, and 13C NMR spectroscopies. Crystal packings and intermolecular interactions for compounds Bu4N[2-B10H9S(CH2COMe)2] and [Ag(PPh3)4][2-B10H9S(CH2COC6H4Cl)2] have been studied using single crystal X-ray diffraction and Hirschfeld surface analysis of the anions.
期刊介绍:
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.