3D Nanowire Pt Catalysts with Enhanced Stability for the Oxygen Reduction Reaction

IF 3.7 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Joshua S. White, Wanli Liu, Samuel C. Perry, Samina Akbar, Diego Alba-Venero, Nicholas J. Terrill, Adam Squires and Iris Nandhakumar*, 
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引用次数: 0

Abstract

We report that self-supporting mesoporous platinum 3D nanowires with a single diamond (SD) morphology and a high specific surface area of 40.4 m2 g–1 demonstrated enhanced stability toward the oxygen reduction reaction (ORR). These were found to be superior to commercially available carbon-supported Pt nanoparticles (Pt/C). After 1000 potential cycles, there was a 21% loss in surface area for SD-Pt, as compared with a 40.3% loss for Pt/C with no reduction in their half-wave potential (measured at J = 3.0 mA cm–2), whereas the Pt/C catalyst showed a 11.9 mV decrease. Our findings revealed that our SD-Pt thin films also exhibited excellent ORR activity, which offers significant potential for their application as high-performance cathode materials in alkaline fuel cells.

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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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