Heteroatom Doping Effects on the Exciton Behavior in Carbonized Polymer Dots

IF 9.6 1区材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Nano Letters Pub Date : 2025-03-03 DOI:10.1021/acs.nanolett.5c00045

Zhihong Wei, Xin Yang, Chengshuang Liao, Feishi Shan, Shengnan Feng, Siyang Ye, Xinlan Hou, Leyong Wang, Xiaoyong Wang, Zhouyu Wang, Siyu Lu, Yuxi Tian

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Abstract

Carbonized polymer dots (CPDs) are attractive optoelectronic materials for a variety of applications, but their complex structures hinder a full understanding of their photophysical and excited-state properties. This work illustrates that heteroatom doping (N-doped, N,S-doped, and N,S,F-doped CPDs) significantly affects the exciton behavior of CPDs. It reveals unconventional photoluminescence (PL) blinking with multilevel intensity fluctuations, which depend on the doping type and excitation power density. The multilevel PL blinking is attributed to the formation of charged excitons induced by heteroatom doping, which resembles the characteristic behavior of semiconductor quantum dots. Additionally, nonradiative recombination enhances photothermal conversion efficiency, enabling effective photothermal therapy with significant cytotoxicity against cancer cells. Our results provide compelling evidence that CPDs possess quantum properties similar to those of semiconductors instead of emissive chromophores on the surface, while also highlighting their multifunctionality as photoluminescent probes and photothermal agents.

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来源期刊

Nano Letters 工程技术-材料科学：综合

CiteScore

16.80

自引率

2.80%

发文量

1182

审稿时长

1.4 months

期刊介绍： Nano Letters serves as a dynamic platform for promptly disseminating original results in fundamental, applied, and emerging research across all facets of nanoscience and nanotechnology. A pivotal criterion for inclusion within Nano Letters is the convergence of at least two different areas or disciplines, ensuring a rich interdisciplinary scope. The journal is dedicated to fostering exploration in diverse areas, including: - Experimental and theoretical findings on physical, chemical, and biological phenomena at the nanoscale - Synthesis, characterization, and processing of organic, inorganic, polymer, and hybrid nanomaterials through physical, chemical, and biological methodologies - Modeling and simulation of synthetic, assembly, and interaction processes - Realization of integrated nanostructures and nano-engineered devices exhibiting advanced performance - Applications of nanoscale materials in living and environmental systems Nano Letters is committed to advancing and showcasing groundbreaking research that intersects various domains, fostering innovation and collaboration in the ever-evolving field of nanoscience and nanotechnology.