Front Cover: Photoredox/Sulfide Dual Catalysis for Modular Synthesis of Multi-substituted Furan Rings via Catalytic Indirect Reductive Quenching (Chem. Asian J. 5/2025)

IF 3.5 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemistry - An Asian Journal Pub Date : 2025-03-03 DOI:10.1002/asia.202580501

Kakeru Matsukuma, Masanori Tayu, Takumi Ogino, Sayaka Ohrui, Masahiro Noji, Satoshi Hayashi, Nozomi Saito

引用次数: 0

Abstract

A catalytic strategy for indirect reductive quenching based on a photoredox and sulfide dual catalysis system has been developed, enabling the synthesis of diverse furan frameworks, including spirofurans and phthalans. Mechanistic studies and DFT calculations revealed the formation of sulfonium species from sulfide radical cations, followed by intramolecular cyclization to construct furan rings. More details can be found in article number e202401442 by Nozomi Saito and co-workers.

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封面：光氧化还原/硫化物双催化间接还原猝灭法合成多取代呋喃环的模块化反应（化学）。亚洲J. 5/2025)

建立了一种基于光氧化还原和硫化物双催化系统的间接还原猝灭催化策略，可以合成多种呋喃骨架，包括螺喃和邻苯二甲酸。机理研究和DFT计算揭示了硫自由基阳离子形成的磺化物质，随后分子内环合形成呋喃环。更多细节可以在Nozomi Saito和同事的文章编号e202401442中找到。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemistry - An Asian Journal 化学-化学综合

CiteScore

7.00

自引率

2.40%

发文量

535

审稿时长

1.3 months

期刊介绍： Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics. Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews. A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal. Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).