{"title":"Fabrication of porous CuxZn1-xS/ GaN heterojunctions for ultraviolet photodetector application","authors":"KaiDa Jia , Wei Jia , TianBao Li , GuangMei Zhai , HengLei Ren , HaiLiang Dong , PengQi Dong , BingShe Xu","doi":"10.1016/j.optmat.2025.116881","DOIUrl":null,"url":null,"abstract":"<div><div>Porous Cu<sub>x</sub>Zn<sub>1-x</sub>S/GaN UV Photodetectors fabricated by a heterojunction between porous n-GaN and Cu<sub>x</sub>Zn<sub>1-x</sub>S films were prepared by high-temperature annealing and chemical bath deposition. By adjusting the ratio of Cu and Zn in the Cu<sub>x</sub>Zn<sub>1-x</sub>S films, with x defined as Cu (mol%)/(Cu + Zn) (mol%), distinct transparency, conductivity, and energy banding properties are achieved, which thereby significantly influences the optoelectronic performance of the UV PDs. The findings of the study demonstrated that the devices exhibit excellent rectification characteristics and repeatable photocurrent responses. When the value of x is 0.4, in particular, exhibits pronounced performances working under an ultraviolet light of 43.5 μW/cm<sup>2</sup> at 0 V, including high on/off ratio (∼5.27 × 10<sup>4</sup>), remarkable responsivity (0.574 A/W), ultrahigh specific detectivity (8.75 × 10<sup>14</sup> Jones), high external quantum efficiency (195.02 %) and fast response speed (0.09/36 ms). This study provides theoretical insights and experimental evidence to facilitate the development of next-generation optoelectronic devices utilizing Cu<sub>x</sub>Zn<sub>1-x</sub>S/GaN heterojunctions.</div></div>","PeriodicalId":19564,"journal":{"name":"Optical Materials","volume":"162 ","pages":"Article 116881"},"PeriodicalIF":3.8000,"publicationDate":"2025-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Optical Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0925346725002411","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Porous CuxZn1-xS/GaN UV Photodetectors fabricated by a heterojunction between porous n-GaN and CuxZn1-xS films were prepared by high-temperature annealing and chemical bath deposition. By adjusting the ratio of Cu and Zn in the CuxZn1-xS films, with x defined as Cu (mol%)/(Cu + Zn) (mol%), distinct transparency, conductivity, and energy banding properties are achieved, which thereby significantly influences the optoelectronic performance of the UV PDs. The findings of the study demonstrated that the devices exhibit excellent rectification characteristics and repeatable photocurrent responses. When the value of x is 0.4, in particular, exhibits pronounced performances working under an ultraviolet light of 43.5 μW/cm2 at 0 V, including high on/off ratio (∼5.27 × 104), remarkable responsivity (0.574 A/W), ultrahigh specific detectivity (8.75 × 1014 Jones), high external quantum efficiency (195.02 %) and fast response speed (0.09/36 ms). This study provides theoretical insights and experimental evidence to facilitate the development of next-generation optoelectronic devices utilizing CuxZn1-xS/GaN heterojunctions.
期刊介绍:
Optical Materials has an open access mirror journal Optical Materials: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review.
The purpose of Optical Materials is to provide a means of communication and technology transfer between researchers who are interested in materials for potential device applications. The journal publishes original papers and review articles on the design, synthesis, characterisation and applications of optical materials.
OPTICAL MATERIALS focuses on:
• Optical Properties of Material Systems;
• The Materials Aspects of Optical Phenomena;
• The Materials Aspects of Devices and Applications.
Authors can submit separate research elements describing their data to Data in Brief and methods to Methods X.