Strategies for the preparation of MOFs-based composites and their research progress in electrocatalysis

IF 4.8 3区材料科学 Q1 CHEMISTRY, APPLIED

Microporous and Mesoporous Materials Pub Date : 2025-02-27 DOI:10.1016/j.micromeso.2025.113560

Tian Zhao, Fuli Luo, Pengcheng Xiao, Saiqun Nie, Jiayao Chen, Yi Chen

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Abstract

This review systematically explores the application and research progress of metal-organic frameworks (MOFs) based composites in electrocatalysis. Firstly, we introduce a variety of preparation methods for MOFs-based composites, including in situ doping/substitution, hydrothermal/solvent-thermal methods, solution impregnation, dual-solvent impregnation, and sandwich assembly, with a focus on analyzing the effects of different methods on the structure and properties of the materials. Secondly, the practical applications of MOFs-based composites in electrocatalytic reactions, including hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, nitrogen reduction reaction, and carbon dioxide reduction, are elaborated in detail, with emphasis on their excellent properties and catalytic mechanisms. Finally, we look forward to the future development trend of MOFs-based composites, and believe that with the emergence of novel synthesis technologies and idealized design methods, MOFs-based composites will show greater potential for applications in areas such as renewable energy conversion and environmental governance. In summary, this review provides a comprehensive perspective and in-depth analysis of the electrocatalytic studies of MOFs-based composites.

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来源期刊

Microporous and Mesoporous Materials 化学-材料科学：综合

CiteScore

10.70

自引率

5.80%

发文量

649

审稿时长

26 days

期刊介绍： Microporous and Mesoporous Materials covers novel and significant aspects of porous solids classified as either microporous (pore size up to 2 nm) or mesoporous (pore size 2 to 50 nm). The porosity should have a specific impact on the material properties or application. Typical examples are zeolites and zeolite-like materials, pillared materials, clathrasils and clathrates, carbon molecular sieves, ordered mesoporous materials, organic/inorganic porous hybrid materials, or porous metal oxides. Both natural and synthetic porous materials are within the scope of the journal. Topics which are particularly of interest include: All aspects of natural microporous and mesoporous solids The synthesis of crystalline or amorphous porous materials The physico-chemical characterization of microporous and mesoporous solids, especially spectroscopic and microscopic The modification of microporous and mesoporous solids, for example by ion exchange or solid-state reactions All topics related to diffusion of mobile species in the pores of microporous and mesoporous materials Adsorption (and other separation techniques) using microporous or mesoporous adsorbents Catalysis by microporous and mesoporous materials Host/guest interactions Theoretical chemistry and modelling of host/guest interactions All topics related to the application of microporous and mesoporous materials in industrial catalysis, separation technology, environmental protection, electrochemistry, membranes, sensors, optical devices, etc.