{"title":"Integrated Multispectral Modulator with Efficient Radiative Cooling for Innovative Thermal Camouflage","authors":"Yilin Ding, Zheyue Mei, Xueke Wu, Wenjing Zhang, Yaqi Zhang, Aike Xi, Di Gao, Fan Lan, Jiaqi Xu, Xungang Diao, Rufan Zhang","doi":"10.1002/adfm.202500122","DOIUrl":null,"url":null,"abstract":"Thermal camouflage technology offers critical countermeasures against infrared detection, yet persistent challenges remain in environmental adaptability, multispectral compatibility, and concurrent thermal management. To address these limitations, a spectrally selective modulator is pioneered that synergistically integrates radiative cooling with electrochromic tunability. The proposed modulator achieves spectrally selective emissivity modulation, demonstrating a remarkable emissivity change (Δ<i>ɛ</i><sub>max</sub> = 0.76) within infrared detection bands (3–5 µm and 8–14 µm) while preserving high emissivity (<i>ɛ</i><sub>max</sub> = 0.79) in non-detection bands for passive heat dissipation. Multispectral operability is further evidenced by dynamic diffuse reflectivity control (<i>R</i><sub>lowest</sub> = 0.07/0.05 across visible and near-infrared band) and terahertz absorptivity modulation (Δ<i>A</i><sub>max</sub> = 0.66), enabling full-spectrum adaptive concealment. The device achieves ≈10 °C apparent temperature modulation without external heating, effectively disguising a 70 °C target as 40 °C. Radiative cooling efficacy is validated through theoretical modeling (peak cooling power: 367 W m<sup>−</sup><sup>2</sup>) and experimental verification (≈6 °C reduction vs conventional wide-spectrum stealth surfaces at 60 °C). With rapid switching (<6 s), exceptional cyclability (>10<sup>3</sup> cycles), and programmable information encryption capabilities. This work resolves the long-standing trade-off between adaptive camouflage and thermal regulation through wavelength-selective emissivity engineering, establishing a versatile foundation for next-generation intelligent camouflage systems across defense, aerospace, and energy-efficient thermal regulation applications.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"210 1","pages":""},"PeriodicalIF":18.5000,"publicationDate":"2025-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Functional Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adfm.202500122","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Thermal camouflage technology offers critical countermeasures against infrared detection, yet persistent challenges remain in environmental adaptability, multispectral compatibility, and concurrent thermal management. To address these limitations, a spectrally selective modulator is pioneered that synergistically integrates radiative cooling with electrochromic tunability. The proposed modulator achieves spectrally selective emissivity modulation, demonstrating a remarkable emissivity change (Δɛmax = 0.76) within infrared detection bands (3–5 µm and 8–14 µm) while preserving high emissivity (ɛmax = 0.79) in non-detection bands for passive heat dissipation. Multispectral operability is further evidenced by dynamic diffuse reflectivity control (Rlowest = 0.07/0.05 across visible and near-infrared band) and terahertz absorptivity modulation (ΔAmax = 0.66), enabling full-spectrum adaptive concealment. The device achieves ≈10 °C apparent temperature modulation without external heating, effectively disguising a 70 °C target as 40 °C. Radiative cooling efficacy is validated through theoretical modeling (peak cooling power: 367 W m−2) and experimental verification (≈6 °C reduction vs conventional wide-spectrum stealth surfaces at 60 °C). With rapid switching (<6 s), exceptional cyclability (>103 cycles), and programmable information encryption capabilities. This work resolves the long-standing trade-off between adaptive camouflage and thermal regulation through wavelength-selective emissivity engineering, establishing a versatile foundation for next-generation intelligent camouflage systems across defense, aerospace, and energy-efficient thermal regulation applications.
期刊介绍:
Firmly established as a top-tier materials science journal, Advanced Functional Materials reports breakthrough research in all aspects of materials science, including nanotechnology, chemistry, physics, and biology every week.
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