Photocatalyst-, Base- and Additive-Free, Visible-Light Induced 1,3-Thiosulfonylation of Allylboronic Esters and Allylketones with Thiosulfonates

IF 4.4 2区化学 Q2 CHEMISTRY, APPLIED

Advanced Synthesis & Catalysis Pub Date : 2025-02-26 DOI:10.1002/adsc.202500051

Xin Zheng, Tuanli Yao, Kaiping Wang, Guodong Zhang, shuilong zhang, Xiang Li

引用次数: 0

Abstract

Abstract. A practical and highly efficient radical 1,3-thiosulfonylation of allylboron esters and allylketones with thiosulfonates via 1,2-functional group migration is described, affording diverse 1,3-thiosulfonylated products in good yields. Notably, this method can be performed under photocatalyst-, base- and additive-free conditions, which features operational simplicity, high atom-economy, excellent functional group tolerance and versatile transformations of the products.

查看原文本刊更多论文

求助全文

约1分钟内获得全文求助全文

来源期刊

Advanced Synthesis & Catalysis 化学-应用化学

CiteScore

9.40

自引率

7.40%

发文量

447

审稿时长

1.8 months

期刊介绍： Advanced Synthesis & Catalysis (ASC) is the leading primary journal in organic, organometallic, and applied chemistry. The high impact of ASC can be attributed to the unique focus of the journal, which publishes exciting new results from academic and industrial labs on efficient, practical, and environmentally friendly organic synthesis. While homogeneous, heterogeneous, organic, and enzyme catalysis are key technologies to achieve green synthesis, significant contributions to the same goal by synthesis design, reaction techniques, flow chemistry, and continuous processing, multiphase catalysis, green solvents, catalyst immobilization, and recycling, separation science, and process development are also featured in ASC. The Aims and Scope can be found in the Notice to Authors or on the first page of the table of contents in every issue.