Constructing Artificial Zincophilic Interphases Based on Indium-Organic Frameworks as Zinc Dendrite Constraint for Rechargeable Zinc-Air Battery.

Abstract

The practical application of zinc (Zn)-air batteries is largely restricted by their inferior cyclability, especially under fast-charging conditions. Uneven Zn plating and dendrite formation result in their short circuits. In this work, an artificial solid-electrolyte interphase (SEI) is constructed using indium-organic frameworks (IOF) on the Zn anode. It contains a hybrid architecture that integrates chemical and morphological contributions to regulate Zn plating behaviors and constrain dendrite growth. The atomically dispersed In³⁺ provides zincophilic sites to tune Zn nucleation kinetics and promote preferential growth along (002) crystal facet. Meanwhile, IOF exhibits nanosheets-assembled microspheres with a well-ordered porous architecture, which promotes mass transfer and affords space for Zn electrodeposition. The influence of SEI microstructure on Zn plating/stripping behavior is further investigated and validated by the post-cycling characterizations. With IOF based SEI, Zn symmetric cells perform stable cycling for over 1750 h at 10 mA cm^-2. When powering Zn-air batteries, their cycling life is extended to 800 h, which is approximately four times longer than that of pristine Zn foil.