Joon Young Kim, Chanmin Jo, Dae Jun Moon, Gyoung Hwa Jeong, Gnanaprakasam Janani, Seungryul Yoo, Dong Chan Seok, Seon Yeop Jung, Tae-Hoon Kim, Ho-Young Jung, Uk Sim
{"title":"ZnPb/C composites coating layer on stainless steel for bipolar plate of unitized regenerative fuel cells","authors":"Joon Young Kim, Chanmin Jo, Dae Jun Moon, Gyoung Hwa Jeong, Gnanaprakasam Janani, Seungryul Yoo, Dong Chan Seok, Seon Yeop Jung, Tae-Hoon Kim, Ho-Young Jung, Uk Sim","doi":"10.1007/s42823-024-00817-y","DOIUrl":null,"url":null,"abstract":"<div><p>For the commercialization of bipolar plates, several properties must be considered together. Electrical conductivity, corrosion resistance, contact resistance, mechanical strength, and light weight are essential evaluation factors, with corrosion resistance and durability being significant for unitized regenerative fuel cells (URFCs), which must operate in electrolysis and fuel cell mode. However, improving both properties is challenging, since corrosion resistance is largely inversely proportional to conductivity. In this study, to improve both properties together, composites composed of Pb and Zn with excellent conductivity and corrosion resistance were prepared with graphite powder and formed as a coating layer on the surface of 304 stainless steel (SS304) and evaluated for electrical conductivity and corrosion resistance. Among the ZnPb/C composites prepared at various ratios, Zn8Pb2/C exhibited the lowest transmittance resistance of 1.566 Ω, and improved electrical conductivity and durability compared to bare SS304.</p></div>","PeriodicalId":506,"journal":{"name":"Carbon Letters","volume":"35 1","pages":"365 - 371"},"PeriodicalIF":5.5000,"publicationDate":"2024-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Carbon Letters","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s42823-024-00817-y","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
For the commercialization of bipolar plates, several properties must be considered together. Electrical conductivity, corrosion resistance, contact resistance, mechanical strength, and light weight are essential evaluation factors, with corrosion resistance and durability being significant for unitized regenerative fuel cells (URFCs), which must operate in electrolysis and fuel cell mode. However, improving both properties is challenging, since corrosion resistance is largely inversely proportional to conductivity. In this study, to improve both properties together, composites composed of Pb and Zn with excellent conductivity and corrosion resistance were prepared with graphite powder and formed as a coating layer on the surface of 304 stainless steel (SS304) and evaluated for electrical conductivity and corrosion resistance. Among the ZnPb/C composites prepared at various ratios, Zn8Pb2/C exhibited the lowest transmittance resistance of 1.566 Ω, and improved electrical conductivity and durability compared to bare SS304.
期刊介绍:
Carbon Letters aims to be a comprehensive journal with complete coverage of carbon materials and carbon-rich molecules. These materials range from, but are not limited to, diamond and graphite through chars, semicokes, mesophase substances, carbon fibers, carbon nanotubes, graphenes, carbon blacks, activated carbons, pyrolytic carbons, glass-like carbons, etc. Papers on the secondary production of new carbon and composite materials from the above mentioned various carbons are within the scope of the journal. Papers on organic substances, including coals, will be considered only if the research has close relation to the resulting carbon materials. Carbon Letters also seeks to keep abreast of new developments in their specialist fields and to unite in finding alternative energy solutions to current issues such as the greenhouse effect and the depletion of the ozone layer. The renewable energy basics, energy storage and conversion, solar energy, wind energy, water energy, nuclear energy, biomass energy, hydrogen production technology, and other clean energy technologies are also within the scope of the journal. Carbon Letters invites original reports of fundamental research in all branches of the theory and practice of carbon science and technology.