Utilizing Near-Field Scanning Optical Microscopy Measurements to Probe Laser Crystallization and Reamorphization in Phase Change Sb2S3 Thin Films

Adrian Podpirka*, Cameron Gutgsell, Gabriella M. Hunt, Robert C. Bruce, David Shrekenhamer, Blake S. Simpkins and Ronald J. Warzoha, 
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Abstract

Phase change materials (PCMs) are seeing tremendous interest for their use in reconfigurable photonic devices. Understanding the volume of the phase change is critical to the construction of devices. In this work, we demonstrate the ability to crystallize and reamorphize Sb2S3 thin films using a 405 nm laser and nondestructively quantify partial volumetric crystallization with nanoscale resolution via near-field scanning optical microscopy (NSOM). We provide an analytical description of the NSOM measurements and correlate the results with a model of laser/Sb2S3 interactions that includes laser irradiance power, thermal transport, and phase change kinetics. The results demonstrate a relationship between computational modeling and physical device behavior, which is critical for the creation of phase change-based devices.

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ACS Applied Optical Materials
ACS Applied Optical Materials 材料科学-光学材料-
CiteScore
1.10
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0.00%
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期刊介绍: ACS Applied Optical Materials is an international and interdisciplinary forum to publish original experimental and theoretical including simulation and modeling research in optical materials complementing the ACS Applied Materials portfolio. With a focus on innovative applications ACS Applied Optical Materials also complements and expands the scope of existing ACS publications that focus on fundamental aspects of the interaction between light and matter in materials science including ACS Photonics Macromolecules Journal of Physical Chemistry C ACS Nano and Nano Letters.The scope of ACS Applied Optical Materials includes high quality research of an applied nature that integrates knowledge in materials science chemistry physics optical science and engineering.
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