Feng Zheng, Mingxin Liu, Yijiang Li*, Jinliu Wei, Xiaoping Chen, Jiancong Ni and Zhixiong Cai*,
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引用次数: 0
Abstract
Thermally activated delayed fluorescence (TADF) materials have garnered significant attention for their capacity to augment electrochemiluminescence (ECL). In this work, three kind of host–guest cocrystals were prepared by incorporating dicyanobenzene (DCB) derivatives as acceptor guests within calix[3]acridan (C[3]A) as donor host. Notably, the ECL signals of C[3]A@o-DCB were significantly stronger than those of C[3]A@p-DCB and C[3]A@m-DCB, attributed to enhanced intermolecular charge transfer (ISCT). Mechanistic investigation, supported by DFT calculations, reveals that the physically separated yet spatially proximate D–A configuration promotes efficient ISCT, leading to enhanced ECL. This study provides insights in designing TADF host–guest cocrystals with favorable properties for ECL.
期刊介绍：
ACS Applied Optical Materials is an international and interdisciplinary forum to publish original experimental and theoretical including simulation and modeling research in optical materials complementing the ACS Applied Materials portfolio. With a focus on innovative applications ACS Applied Optical Materials also complements and expands the scope of existing ACS publications that focus on fundamental aspects of the interaction between light and matter in materials science including ACS Photonics Macromolecules Journal of Physical Chemistry C ACS Nano and Nano Letters.The scope of ACS Applied Optical Materials includes high quality research of an applied nature that integrates knowledge in materials science chemistry physics optical science and engineering.
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