A Novel Methodology to Quantify the Slag Protective Effect on the Oxidation Behavior of Oxide-C Refractories

Abstract

Preventing the oxidation of oxide-C refractories used as working linings in steelmaking vessels is crucial for maintaining their performance and extending their lifetime. This study introduces a novel methodology for evaluating and quantifying the protective effect that adhered slag can have on the oxidation of the refractory lining of steelmaking ladles. The article details the ad-hoc methodology itself, including the technique for adhering the slag to the refractory sample and the specifically developed equipment used. The proposed experimental approach includes the evaluation of how the environmental degradation of the slag layer affects the protection it provides to the refractory against attack by environmental oxygen. Finally, the methodology's ability to provide reliable and reproducible results is shown by its application on MgO–C refractories, the most widely used type of oxide-C products in the steelmaking industry.