MOF-derived carbon-coated NiS/NiS2 yolk-shell spheres as a satisfactory positive electrode material for hybrid supercapacitors

IF 23.2 2区材料科学 Q1 MATERIALS SCIENCE, COMPOSITES

Advanced Composites and Hybrid Materials Pub Date : 2025-02-27 DOI:10.1007/s42114-025-01257-6

Jing Wang, Shuo Li, Ning Fu, Dayong Tian, Yong Zheng, Fang Wang, Chao Liu, Xiaolong Wang, Zhongyuan Zhou, Yongsheng Niu, Hao Liu, Guoxiu Wang, Shichun Mu, Jiahuan Luo

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Abstract

Optimizing the performance of electrode materials to improve the energy density of supercapacitors is the focus of current research. Construction and design with complex yolk-shell structure, as a supercapacitor electrode material, are of great significance and challenging. Herein, a self-sacrificing template strategy was used to construct uniform carbon-modified NiS/NiS₂ yolk-shell spheres using a Ni-based metal–organic framework (Ni-soc-MOF) as the precursors. Especially, the carbon shells produced by the pyrolysis of the organic ligand can improve mechanical stability and electron conductivity. Therefore, the as-obtained NiS/NiS₂@C nanocomposites display a high specific capacity (1082 C g⁻¹at 1 A g⁻¹) and outstanding cycling stability (85% capacity retention after 5000 cycles). In addition, a hybrid supercapacitor device based on the yolk-shell NiS/NiS₂@C nanocomposite and porous carbon can deliver a high energy density of 56.2 Wh kg⁻¹ at 800 W kg⁻¹, while exhibiting an excellent capacity retention of 86% after 10,000 charge/discharge cycles, demonstrating the promising potential of yolk-shell NiS/NiS₂@C nanocomposites via Ni-soc-MOF-derived route in practical application.

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来源期刊

Advanced Composites and Hybrid Materials Multiple-

CiteScore

26.00

自引率

21.40%

发文量

185

期刊介绍： Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.