Recent Advances in Desulfurization of VOSCs: Multiple Catalysts and Coupling Enzymes

IF 11.3 1区化学 Q1 CHEMISTRY, PHYSICAL

ACS Catalysis Pub Date : 2025-02-26 DOI:10.1021/acscatal.4c08111

Rui Tian, Shiying Fan, Xinyong Li, Shaomin Liu

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引用次数: 0

Abstract

The presence of volatile organic sulfur compounds (VOSCs) poses serious hazards to both the environment and human health, highlighting the importance and urgency of developing efficient abatement technologies. Effective desulfurization catalysts should demonstrate sufficient catalytic activity at low temperatures, high selectivity, and robust resistance to carbon and sulfur. Achieving these attributes needs careful optimization of three key factors of the catalysts: acidity, redox properties, and active oxygen species. In this review, we explore the design and optimization of multiple catalysts by focusing on the three key factors mentioned. We also discuss the synergistic degradation of multicomponent VOSCs, along with the mechanism of catalytic reaction, catalyst deactivation, and regeneration. It is noteworthy that an innovative catalysis at room temperature is highlighted, which combines chemical and biological methods to enhance the desulfurization performance through the integration of enzymes and inorganic components. The catalytic reaction mechanism and the catalyst design by coupling the biological enzymes and inorganic substances to achieve room catalysis is systemically elaborated. It is hopeful that this review will inspire researchers in academia and industry and promote their collaborations to address future environmental desulfurization challenges by combining chemical and biological approaches.

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来源期刊

ACS Catalysis CHEMISTRY, PHYSICAL-

CiteScore

20.80

自引率

6.20%

发文量

1253

审稿时长

1.5 months

期刊介绍： ACS Catalysis is an esteemed journal that publishes original research in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. It offers broad coverage across diverse areas such as life sciences, organometallics and synthesis, photochemistry and electrochemistry, drug discovery and synthesis, materials science, environmental protection, polymer discovery and synthesis, and energy and fuels. The scope of the journal is to showcase innovative work in various aspects of catalysis. This includes new reactions and novel synthetic approaches utilizing known catalysts, the discovery or modification of new catalysts, elucidation of catalytic mechanisms through cutting-edge investigations, practical enhancements of existing processes, as well as conceptual advances in the field. Contributions to ACS Catalysis can encompass both experimental and theoretical research focused on catalytic molecules, macromolecules, and materials that exhibit catalytic turnover.