From Single-Chain Polymeric Nanoparticles to Interpenetrating Polymer Network Organogels: A One-Pot Fabrication Approach.

IF 5 3区化学 Q1 POLYMER SCIENCE

Gels Pub Date : 2025-02-07 DOI:10.3390/gels11020122

Selin Daglar, Demet Karaca Balta, Binnur Aydogan Temel, Gokhan Temel

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引用次数: 0

Abstract

In this study, we developed a novel one-pot synthesis method to fabricate well-defined single-chain polymeric nanoparticles (SCNPs) integrated with interpenetrating polymer network (IPN) systems. The synthesis process involved an initial intramolecular crosslinking of poly(methyl methacrylate-co-glycidyl methacrylate) to form SCNP followed by intermolecular crosslinking to produce single-chain nanogel (SCNG) structures. In addition, the achieved single-chain polymeric nanoparticle was subsequently incorporated into an IPN structure through urethane bond formation and a Diels-Alder click reaction involving furfuryl methacrylate (FMA) and bismaleimide (BMI). The thermal properties, swelling behaviors, and morphologies of the resulting SCNP-IPN systems were investigated. This work presents a novel strategy that integrates the single-chain folding concept with IPN systems, providing a promising platform for the development of robust and functional polymeric materials with potential applications in advanced materials science.

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从单链聚合物纳米颗粒到互穿聚合物网络有机凝胶：一锅制备方法。

在这项研究中，我们开发了一种新的一锅合成方法来制备具有互穿聚合物网络（IPN）系统的单链聚合物纳米粒子（SCNPs）。合成过程包括最初的分子内交联聚甲基丙烯酸甲酯-甲基丙烯酸缩水甘油酯形成SCNP，然后分子间交联产生单链纳米凝胶（SCNG）结构。此外，所获得的单链聚合物纳米颗粒随后通过氨基甲酸乙酯键形成和Diels-Alder点击反应（涉及甲基丙烯酸糠酯（FMA）和双马来酰亚胺（BMI））被纳入IPN结构。研究了所得到的SCNP-IPN体系的热性能、膨胀行为和形貌。这项工作提出了一种将单链折叠概念与IPN系统相结合的新策略，为开发具有强大功能的聚合物材料提供了一个有前途的平台，在先进材料科学中具有潜在的应用前景。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Gels POLYMER SCIENCE-

CiteScore

4.70

自引率

19.60%

发文量

707

审稿时长

11 weeks

期刊介绍： The journal Gels (ISSN 2310-2861) is an international, open access journal on physical (supramolecular) and chemical gel-based materials. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the maximum length of the papers, and full experimental details must be provided so that the results can be reproduced. Short communications, full research papers and review papers are accepted formats for the preparation of the manuscripts. Gels aims to serve as a reference journal with a focus on gel materials for researchers working in both academia and industry. Therefore, papers demonstrating practical applications of these materials are particularly welcome. Occasionally, invited contributions (i.e., original research and review articles) on emerging issues and high-tech applications of gels are published as special issues.