Preparation, structural characterizations and surface studies of irradiated flexible PPy/Fe2O3/PET polymer nanocomposite films for dielectric applications

IF 2.8 4区工程技术 Q2 POLYMER SCIENCE

Macromolecular Research Pub Date : 2024-09-20 DOI:10.1007/s13233-024-00323-0

E. Abdeltwab, Nuha Al-Harbi, A. Atta, M. M. Abdelhamied

{"title":"Preparation, structural characterizations and surface studies of irradiated flexible PPy/Fe2O3/PET polymer nanocomposite films for dielectric applications","authors":"E. Abdeltwab, Nuha Al-Harbi, A. Atta, M. M. Abdelhamied","doi":"10.1007/s13233-024-00323-0","DOIUrl":null,"url":null,"abstract":"<div><p>A new composite (PPy/Fe<sub>2</sub>O<sub>3</sub>)/PET was created by mixing polypyrrole (PPy) with iron oxide (Fe<sub>2</sub>O<sub>3</sub>) and then depositing the resulting blend (PPy/Fe<sub>2</sub>O<sub>3</sub>) onto a polyethylene terephthalate (PET). After utilizing oxidative chemical polymerization to construct the composite, the samples were examined using X-ray diffraction (XRD), X-ray photoelectron (XPS), and infrared (FTIR) techniques. The XRD confirms that the (PPy/Fe<sub>2</sub>O<sub>3</sub>)/PET composites were successfully fabricated. The conductivity of PET is 4 × 10<sup>−8</sup> S·cm<sup>−1</sup>, increased for the composites (PPy/Fe<sub>2</sub>O<sub>3</sub>)/PET to 6.1 × 10<sup>−5</sup> S·cm<sup>−1</sup>. Additionally, the effects of argon beam bombardment with cold cathode sources (4 × 10<sup>16</sup>, 6 × 10<sup>16</sup>, and 8 × 10<sup>16</sup> ions.cm<sup>−2</sup>) on (PPy/Fe<sub>2</sub>O<sub>3</sub>)/PET composites were investigated. Furthermore, the surface energy and the contact angle were determined. As a result of this study, irradiated nanocomposite films have new physico-chemical characteristics that may find uses in the storage energy devices. The results showed that the irradiated composite are greatly improved, allowing these films to be used for a range of applications, including coating and printing devices.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":688,"journal":{"name":"Macromolecular Research","volume":"33 2","pages":"195 - 205"},"PeriodicalIF":2.8000,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecular Research","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s13233-024-00323-0","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}

引用次数: 0

Abstract

A new composite (PPy/Fe₂O₃)/PET was created by mixing polypyrrole (PPy) with iron oxide (Fe₂O₃) and then depositing the resulting blend (PPy/Fe₂O₃) onto a polyethylene terephthalate (PET). After utilizing oxidative chemical polymerization to construct the composite, the samples were examined using X-ray diffraction (XRD), X-ray photoelectron (XPS), and infrared (FTIR) techniques. The XRD confirms that the (PPy/Fe₂O₃)/PET composites were successfully fabricated. The conductivity of PET is 4 × 10⁻⁸ S·cm⁻¹, increased for the composites (PPy/Fe₂O₃)/PET to 6.1 × 10⁻⁵ S·cm⁻¹. Additionally, the effects of argon beam bombardment with cold cathode sources (4 × 10¹⁶, 6 × 10¹⁶, and 8 × 10¹⁶ ions.cm⁻²) on (PPy/Fe₂O₃)/PET composites were investigated. Furthermore, the surface energy and the contact angle were determined. As a result of this study, irradiated nanocomposite films have new physico-chemical characteristics that may find uses in the storage energy devices. The results showed that the irradiated composite are greatly improved, allowing these films to be used for a range of applications, including coating and printing devices.

Graphical abstract

查看原文本刊更多论文

介质用辐照柔性PPy/Fe2O3/PET聚合物纳米复合薄膜的制备、结构表征和表面研究

将聚吡咯（PPy）与氧化铁（Fe2O3）混合，然后将所得混合物（PPy/Fe2O3）沉积在聚对苯二甲酸乙二醇酯（PET）上，制备了一种新的复合材料(PPy/Fe2O3)/PET。利用氧化化学聚合法制备复合材料后，利用x射线衍射（XRD）、x射线光电子（XPS）和红外（FTIR）技术对样品进行了检测。XRD证实了(PPy/Fe2O3)/PET复合材料的成功制备。PET的电导率为4 × 10−8 S·cm−1，复合材料(PPy/Fe2O3)/PET的电导率为6.1 × 10−5 S·cm−1。此外，研究了冷阴极源氩束轰击（4 × 1016、6 × 1016和8 × 1016离子。cm−2）对(PPy/Fe2O3)/PET复合材料的影响。测定了表面能和接触角。研究结果表明，辐照纳米复合薄膜具有新的物理化学特性，可用于储能器件。结果表明，辐照复合材料得到了极大的改善，使这些薄膜可用于一系列应用，包括涂层和印刷设备。图形抽象

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Macromolecular Research 工程技术-高分子科学

CiteScore

4.70

自引率

8.30%

发文量

100

审稿时长

1.3 months

期刊介绍： Original research on all aspects of polymer science, engineering and technology, including nanotechnology Presents original research articles on all aspects of polymer science, engineering and technology Coverage extends to such topics as nanotechnology, biotechnology and information technology The English-language journal of the Polymer Society of Korea Macromolecular Research is a scientific journal published monthly by the Polymer Society of Korea. Macromolecular Research publishes original researches on all aspects of polymer science, engineering, and technology as well as new emerging technologies using polymeric materials including nanotechnology, biotechnology, and information technology in forms of Articles, Communications, Notes, Reviews, and Feature articles.