Ionic Liquid-Functionalized Periodic Mesoporous Organosilica: A Robust Support for Palladium Nanoparticles in Carbonylative Suzuki Coupling Reactions.

IF 3.5 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemistry - An Asian Journal Pub Date : 2025-02-24 DOI:10.1002/asia.202401802

Manan Sohanwal, Suheir Omar, Raed Abu-Reziq

{"title":"Ionic Liquid-Functionalized Periodic Mesoporous Organosilica: A Robust Support for Palladium Nanoparticles in Carbonylative Suzuki Coupling Reactions.","authors":"Manan Sohanwal, Suheir Omar, Raed Abu-Reziq","doi":"10.1002/asia.202401802","DOIUrl":null,"url":null,"abstract":"This study presents the synthesis and application of palladium nanoparticles (Pd NPs) supported on ionic-liquid-functionalized periodic mesoporous organosilica (PMO-IL) as an efficient heterogeneous catalyst for carbonylative Suzuki coupling reactions. The PMO-IL material was prepared via a sol-gel polycondensation process using tetraethyl orthosilicate (TEOS) and a bis-silylated ionic liquid monomer. The ionic liquid groups within the PMO framework facilitated the adsorption of palladium salts through ion exchange, followed by reduction to form Pd NPs. Comprehensive characterization of the Pd(np)@PMO-IL system, including high-resolution microscopy (HR-SEM and HR-TEM), X-ray diffraction (XRD), solid-state NMR, FT-IR, and nitrogen adsorption-desorption (BET) analyses, confirmed its structure, morphology, and high surface area. The catalytic system demonstrated remarkable activity, selectivity, and recyclability in the carbonylative Suzuki coupling reaction, achieving high turnover numbers (TON) and turnover frequencies (TOF) under mild conditions. This hybrid material highlights the potential of ionic liquid-functionalized PMOs as versatile supports for metal nanoparticles in sustainable catalytic applications.","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":" ","pages":"e202401802"},"PeriodicalIF":3.5000,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry - An Asian Journal","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1002/asia.202401802","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

This study presents the synthesis and application of palladium nanoparticles (Pd NPs) supported on ionic-liquid-functionalized periodic mesoporous organosilica (PMO-IL) as an efficient heterogeneous catalyst for carbonylative Suzuki coupling reactions. The PMO-IL material was prepared via a sol-gel polycondensation process using tetraethyl orthosilicate (TEOS) and a bis-silylated ionic liquid monomer. The ionic liquid groups within the PMO framework facilitated the adsorption of palladium salts through ion exchange, followed by reduction to form Pd NPs. Comprehensive characterization of the Pd_(np)@PMO-IL system, including high-resolution microscopy (HR-SEM and HR-TEM), X-ray diffraction (XRD), solid-state NMR, FT-IR, and nitrogen adsorption-desorption (BET) analyses, confirmed its structure, morphology, and high surface area. The catalytic system demonstrated remarkable activity, selectivity, and recyclability in the carbonylative Suzuki coupling reaction, achieving high turnover numbers (TON) and turnover frequencies (TOF) under mild conditions. This hybrid material highlights the potential of ionic liquid-functionalized PMOs as versatile supports for metal nanoparticles in sustainable catalytic applications.

查看原文本刊更多论文

求助全文

约1分钟内获得全文求助全文

来源期刊

Chemistry - An Asian Journal 化学-化学综合

CiteScore

7.00

自引率

2.40%

发文量

535

审稿时长

1.3 months

期刊介绍： Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics. Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews. A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal. Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).