The amorphization strategies of two-dimensional transition metal oxide/(oxy)hydroxide nanomaterials for enhanced electrocatalytic water splitting

IF 9.6 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Rare Metals Pub Date : 2025-01-31 DOI:10.1007/s12598-024-03082-0

Si-Bin Duan, Yu-Qing Wang, Rui Cao, Yi-Fei Sun, Wen Zhang, Rong-Ming Wang

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Abstract

Amorphous two-dimensional transition metal oxide/(oxy)hydroxide (2D TMO/TMHO) nanomaterials (NMs) have the properties of both 2D and amorphous materials, displaying outstanding physicochemical qualities. Therefore, they demonstrate considerable promise for use in electrocatalytic water splitting applications. Here, the primary amorphization strategies for achieving the 2D TMO/TMHO NMs are comprehensively reviewed, including low-temperature reaction, rapid reaction, exchange/doping effect, ligand modulation, and interfacial energy confinement. By integrating these strategies with various physicochemical synthesis methods, it is feasible to control the amorphization of TMO/TMHO NMs while maintaining the distinctive benefits of their 2D structures. Furthermore, it delves into the structural advantages of amorphous 2D TMO/TMHO NMs in electrocatalytic water splitting, particularly emphasizing recent advancements in enhancing their electrocatalytic performance through interface engineering. The challenges and potential future directions for the precise synthesis and practical application of amorphous 2D TMO/TMHO NMs are also provided. This review aims to establish a theoretical foundation and offer experimental instructions for developing effective and enduring electrocatalysts for water splitting.

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来源期刊

Rare Metals 工程技术-材料科学：综合

CiteScore

12.10

自引率

12.50%

发文量

2919

审稿时长

2.7 months

期刊介绍： Rare Metals is a monthly peer-reviewed journal published by the Nonferrous Metals Society of China. It serves as a platform for engineers and scientists to communicate and disseminate original research articles in the field of rare metals. The journal focuses on a wide range of topics including metallurgy, processing, and determination of rare metals. Additionally, it showcases the application of rare metals in advanced materials such as superconductors, semiconductors, composites, and ceramics.