Synthesis, Characterization, and Fabrication of Linear Nanofiber Structure of Poly(vinylidene fluoride)/MgO Copolymer via Electrospinning Method

IF 2.1 4区材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY

JOM Pub Date : 2025-01-06 DOI:10.1007/s11837-024-07095-z

Asnan Rinovian, Merita Merita, Arniati Labanni, Sriyono Sriyono, Nurrahmi Handayani, Muhammad Amin, Heryanto Heryanto, Dahlang Tahir, Muhamad Nasir

{"title":"Synthesis, Characterization, and Fabrication of Linear Nanofiber Structure of Poly(vinylidene fluoride)/MgO Copolymer via Electrospinning Method","authors":"Asnan Rinovian, Merita Merita, Arniati Labanni, Sriyono Sriyono, Nurrahmi Handayani, Muhammad Amin, Heryanto Heryanto, Dahlang Tahir, Muhamad Nasir","doi":"10.1007/s11837-024-07095-z","DOIUrl":null,"url":null,"abstract":"<div><p>Poly(vinylidene fluoride)/MgO copolymer nanofiber composites have been successfully synthesized with MgO nanoparticles (MgO NPs) variations using the electrospinning method as a promising strategy to obtain nanofiber models. The quantitative analysis of the FTIR spectrum using the Kramers–Kronig (K–K) relationship shows that the change of <span>\\(\\Delta \\left(\\text{LO}-\\text{TO}\\right)\\)</span> from (139 → 114) cm<sup>−1</sup> indicates the change of strain, crystal symmetry, and phase transition. The crystallinity index increased (26.9 → 31)% caused by the increased concentration of MgO NPs in the composites rose as the result of XRD spectra analysis. The SEM analysis has provided valuable insights into the morphology of cPVDF nanofibers, demonstrating their predominantly linear structure while the influence of MgO concentration on nanofiber diameter decreased (621 → 347) nm. Based on the results, an increase in MgO concentration, a higher vibrational range of optical phonons, and an increase in crystallinity index successfully produced a copolymer material structure dominated by a linear nanofiber structure.</p></div>","PeriodicalId":605,"journal":{"name":"JOM","volume":"77 3","pages":"1367 - 1375"},"PeriodicalIF":2.1000,"publicationDate":"2025-01-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"JOM","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11837-024-07095-z","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

Poly(vinylidene fluoride)/MgO copolymer nanofiber composites have been successfully synthesized with MgO nanoparticles (MgO NPs) variations using the electrospinning method as a promising strategy to obtain nanofiber models. The quantitative analysis of the FTIR spectrum using the Kramers–Kronig (K–K) relationship shows that the change of \(\Delta \left(\text{LO}-\text{TO}\right)\) from (139 → 114) cm⁻¹ indicates the change of strain, crystal symmetry, and phase transition. The crystallinity index increased (26.9 → 31)% caused by the increased concentration of MgO NPs in the composites rose as the result of XRD spectra analysis. The SEM analysis has provided valuable insights into the morphology of cPVDF nanofibers, demonstrating their predominantly linear structure while the influence of MgO concentration on nanofiber diameter decreased (621 → 347) nm. Based on the results, an increase in MgO concentration, a higher vibrational range of optical phonons, and an increase in crystallinity index successfully produced a copolymer material structure dominated by a linear nanofiber structure.

查看原文本刊更多论文

电纺丝法合成、表征和制造聚偏氟乙烯/氧化镁共聚物的线性纳米纤维结构

聚偏氟乙烯/MgO共聚物纳米纤维复合材料采用静电纺丝法制备了MgO纳米颗粒（MgO NPs），是一种很有前途的纳米纤维模型制备方法。利用Kramers-Kronig （K-K）关系对FTIR光谱进行定量分析表明，\(\Delta \left(\text{LO}-\text{TO}\right)\)从（139→114）cm−1的变化表明了应变、晶体对称性和相变的变化。结晶度指数增加（26.9→31）% caused by the increased concentration of MgO NPs in the composites rose as the result of XRD spectra analysis. The SEM analysis has provided valuable insights into the morphology of cPVDF nanofibers, demonstrating their predominantly linear structure while the influence of MgO concentration on nanofiber diameter decreased (621 → 347) nm. Based on the results, an increase in MgO concentration, a higher vibrational range of optical phonons, and an increase in crystallinity index successfully produced a copolymer material structure dominated by a linear nanofiber structure.

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

JOM 工程技术-材料科学：综合

CiteScore

4.50

自引率

3.80%

发文量

540

审稿时长

2.8 months

期刊介绍： JOM is a technical journal devoted to exploring the many aspects of materials science and engineering. JOM reports scholarly work that explores the state-of-the-art processing, fabrication, design, and application of metals, ceramics, plastics, composites, and other materials. In pursuing this goal, JOM strives to balance the interests of the laboratory and the marketplace by reporting academic, industrial, and government-sponsored work from around the world.