Synthesis, Characterization, and Fabrication of Linear Nanofiber Structure of Poly(vinylidene fluoride)/MgO Copolymer via Electrospinning Method

IF 2.1 4区材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY

JOM Pub Date : 2025-01-06 DOI:10.1007/s11837-024-07095-z

Asnan Rinovian, Merita Merita, Arniati Labanni, Sriyono Sriyono, Nurrahmi Handayani, Muhammad Amin, Heryanto Heryanto, Dahlang Tahir, Muhamad Nasir

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引用次数: 0

Abstract

Poly(vinylidene fluoride)/MgO copolymer nanofiber composites have been successfully synthesized with MgO nanoparticles (MgO NPs) variations using the electrospinning method as a promising strategy to obtain nanofiber models. The quantitative analysis of the FTIR spectrum using the Kramers–Kronig (K–K) relationship shows that the change of \(\Delta \left(\text{LO}-\text{TO}\right)\) from (139 → 114) cm⁻¹ indicates the change of strain, crystal symmetry, and phase transition. The crystallinity index increased (26.9 → 31)% caused by the increased concentration of MgO NPs in the composites rose as the result of XRD spectra analysis. The SEM analysis has provided valuable insights into the morphology of cPVDF nanofibers, demonstrating their predominantly linear structure while the influence of MgO concentration on nanofiber diameter decreased (621 → 347) nm. Based on the results, an increase in MgO concentration, a higher vibrational range of optical phonons, and an increase in crystallinity index successfully produced a copolymer material structure dominated by a linear nanofiber structure.

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电纺丝法合成、表征和制造聚偏氟乙烯/氧化镁共聚物的线性纳米纤维结构

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来源期刊

JOM 工程技术-材料科学：综合

CiteScore

4.50

自引率

3.80%

发文量

540

审稿时长

2.8 months

期刊介绍： JOM is a technical journal devoted to exploring the many aspects of materials science and engineering. JOM reports scholarly work that explores the state-of-the-art processing, fabrication, design, and application of metals, ceramics, plastics, composites, and other materials. In pursuing this goal, JOM strives to balance the interests of the laboratory and the marketplace by reporting academic, industrial, and government-sponsored work from around the world.