Graphene oxide/chitosan hydrogels for removal of antibiotics.

Abstract

Antibiotic contamination in aquatic environments is a growing concern, posing risks to public health and ecosystems. To address this issue, advanced materials like graphene oxide (GO) and chitosan-based hydrogels are being extensively explored for their ability to effectively remove antibiotics from wastewater, owing to their distinct characteristics and synergistic benefits. This review comprehensively examines the synthesis, characterization, and applications of GO/chitosan hydrogels in addressing antibiotic pollution. The synthesis methods, including solution casting, crosslinking, and in situ polymerization, are discussed for their simplicity and scalability. The hydrogels' key properties, such as porosity, surface area, and mechanical strength, are essential for their efficient adsorption capabilities. Adsorption mechanisms, including electrostatic interactions, π-π stacking, hydrogen bonding, and surface functional groups, enable these hydrogels to achieve high adsorption capacities. Notable examples include rGO@ZIF-67@CS hydrogels, which achieved higher adsorption capacities of 1685.26 mg·g^-1 for tetracycline at pH 4 and 1890.32 mg·g^-1 for norfloxacin at pH 5, while the sulfonated CMC/GO-GCC composite hydrogel achieved 312.28 mg·g^-1 for sulfamethoxazole at 298 K. Moreover, high adsorption efficiencies of 90.42% with GO-CTS and 97.06% were achieved using AGO-CTS hydrogel for diclofenac adsorption. The review also highlights the practical applications of these hydrogels in wastewater treatment, comparing their performance with other adsorbents and addressing challenges such as scalability and regeneration. Finally, the review explores future research directions to enhance the effectiveness and sustainability of GO/chitosan hydrogels, emphasizing their potential as scalable, eco-friendly solutions for antibiotic removal from water.