Photoacids and Photobases: Applications in Functional Dynamic Systems

Abstract

Brønsted photoacids and photobases are a unique class of molecules that undergo a major change in their pK_a values between their ground and excited states, resulting in donating or accepting a proton, respectively, but only after light excitation. This property of photoacids/photobases makes them an attractive tool for light-gating various dynamic processes. Here, we review the use of this property to manipulate functional dynamic systems with light. We discuss how a proton transfer event that can happen upon light excitation from a photoacid to a chemical moiety of a certain system or, vice versa, from the system to a photobase, can result in a shift in the equilibrium of the system, resulting in some dynamicity. We detail various systems, including self-assembly processes of nanostructures, self-propulsion of droplets, catalysis for hydrogen evolution or CO₂ capturing, nanotechnological devices based on enzymatic processes, and changes in proton-conducting ionophores and materials. We detail the basic guidelines for using Brønsted photoacids and photobases in a desired system and conclude with the current technological gaps in further using these molecules.