{"title":"The Interplay of Methylidyne and Carbido Species: Modeling a Fundamental Step in the Fischer–Tropsch Synthesis","authors":"Dr. Liam K. Burt, Prof. Dr. Anthony F. Hill","doi":"10.1002/ange.202424699","DOIUrl":null,"url":null,"abstract":"<p>Heterobimetallic μ-methylidyne complexes [WPt(μ<sub>2</sub>-CH)(CO)<sub>2</sub>L<sub>2</sub>(Tp*)], where L<sub>2</sub>=(PPh<sub>3</sub>)<sub>2</sub>, (PPh<sub>3</sub>)(CO), (dppe), (PPh<sub>3</sub>)(CNC<sub>6</sub>H<sub>2</sub>Me<sub>3</sub>), have been obtained via the intermediacy of transient hydrido-μ-carbido complexes that undergo carbido-hydrido coupling to model a fundamental step in the proposed mechanism for Fischer–Tropsch synthesis.</p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 9","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202424699","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202424699","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Heterobimetallic μ-methylidyne complexes [WPt(μ2-CH)(CO)2L2(Tp*)], where L2=(PPh3)2, (PPh3)(CO), (dppe), (PPh3)(CNC6H2Me3), have been obtained via the intermediacy of transient hydrido-μ-carbido complexes that undergo carbido-hydrido coupling to model a fundamental step in the proposed mechanism for Fischer–Tropsch synthesis.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
