From Fundamentals to Synthesis: Covalent Organic Frameworks as Promising Materials for CO2 Adsorption

IF 8.6 2区化学 Q1 Chemistry

Topics in Current Chemistry Pub Date : 2025-02-22 DOI:10.1007/s41061-025-00494-z

Awais Ali Aslam, Sania Amjad, Adnan Irshad, Osama Kokab, Mudassar Sana Ullah, Awais Farid, Rana Adeel Mehmood, Sadaf Ul Hassan, Muhammad Shahid Nazir, Mahmood Ahmed

{"title":"From Fundamentals to Synthesis: Covalent Organic Frameworks as Promising Materials for CO2 Adsorption","authors":"Awais Ali Aslam, Sania Amjad, Adnan Irshad, Osama Kokab, Mudassar Sana Ullah, Awais Farid, Rana Adeel Mehmood, Sadaf Ul Hassan, Muhammad Shahid Nazir, Mahmood Ahmed","doi":"10.1007/s41061-025-00494-z","DOIUrl":null,"url":null,"abstract":"<div><p>Covalent organic frameworks (COFs) are highly crystalline polymers that possess exceptional porosity and surface area, making them a subject of significant research interest. COF materials are synthesized by chemically linking organic molecules in a repetitive arrangement, creating a highly effective porous crystalline structure that adsorbs and retains gases. They are highly effective in removing impurities, such as CO<sub>2</sub>, because of their desirable characteristics, such as durability, high reactivity, stable porosity, and increased surface area. This study offers a background overview, encompassing a concise discussion of the current issue of excessive carbon emissions, and a synopsis of the materials most frequently used for CO<sub>2</sub> collection. This review provides a detailed overview of COF materials, particularly emphasizing their synthesis methods and applications in carbon capture. It presents the latest research findings on COFs synthesized using various covalent bond formation techniques. Moreover, it discusses emerging trends and future prospects in this particular field.</p><h3>Graphical abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":802,"journal":{"name":"Topics in Current Chemistry","volume":"383 1","pages":""},"PeriodicalIF":8.6000,"publicationDate":"2025-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Topics in Current Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s41061-025-00494-z","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Chemistry","Score":null,"Total":0}

引用次数: 0

Abstract

Covalent organic frameworks (COFs) are highly crystalline polymers that possess exceptional porosity and surface area, making them a subject of significant research interest. COF materials are synthesized by chemically linking organic molecules in a repetitive arrangement, creating a highly effective porous crystalline structure that adsorbs and retains gases. They are highly effective in removing impurities, such as CO₂, because of their desirable characteristics, such as durability, high reactivity, stable porosity, and increased surface area. This study offers a background overview, encompassing a concise discussion of the current issue of excessive carbon emissions, and a synopsis of the materials most frequently used for CO₂ collection. This review provides a detailed overview of COF materials, particularly emphasizing their synthesis methods and applications in carbon capture. It presents the latest research findings on COFs synthesized using various covalent bond formation techniques. Moreover, it discusses emerging trends and future prospects in this particular field.

Graphical abstract

查看原文本刊更多论文

从基础到合成：共价有机框架作为有前途的CO2吸附材料

共价有机框架（COFs）是一种高度结晶的聚合物，具有特殊的孔隙率和表面积，使其成为重要的研究兴趣课题。COF材料是通过重复排列有机分子的化学连接来合成的，创造了一种高效的多孔晶体结构，可以吸附和保留气体。它们在去除杂质（如CO2）方面非常有效，因为它们具有理想的特性，如耐用性、高反应性、稳定的孔隙度和增加的表面积。本研究提供了一个背景概述，包括对当前过度碳排放问题的简要讨论，以及最常用于二氧化碳收集的材料的概述。本文综述了碳纳米管材料的研究现状，重点介绍了碳纳米管材料的合成方法及其在碳捕获中的应用。介绍了利用各种共价键形成技术合成COFs的最新研究成果。此外，它还讨论了这一特定领域的新趋势和未来前景。图形抽象

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Topics in Current Chemistry 化学-化学综合

CiteScore

11.70

自引率

1.20%

发文量

审稿时长

6-12 weeks

期刊介绍： Topics in Current Chemistry provides in-depth analyses and forward-thinking perspectives on the latest advancements in chemical research. This renowned journal encompasses various domains within chemical science and their intersections with biology, medicine, physics, and materials science. Each collection within the journal aims to offer a comprehensive understanding, accessible to both academic and industrial readers, of emerging research in an area that captivates a broader scientific community. In essence, Topics in Current Chemistry illuminates cutting-edge chemical research, fosters interdisciplinary collaboration, and facilitates knowledge-sharing among diverse scientific audiences.