{"title":"Influence of nitrogen contents in fuel and oxidizer on nitrogen oxide emissions during NG/O2 combustion","authors":"Wontak Choi , Seunggi Choi , Yonmo Sung","doi":"10.1016/j.csite.2025.105868","DOIUrl":null,"url":null,"abstract":"<div><div>This study aims to understand the NO<sub>x</sub> emission characteristics during pure oxygen (O<sub>2</sub>) combustion of natural gas (NG) and to provide design data for application in forging furnaces. We numerically investigated the sensitivity of NO<sub>x</sub> emissions to an up to 10 % increase in nitrogen (N<sub>2</sub>) content of the fuel and oxidizer. According to the impact analysis, the two cases have a more adverse effect on NO<sub>x</sub> emissions. The numerical model established in this study was verified using experimental results obtained by the International Flame Research Foundation (IFRF). In addition, the N<sub>2</sub> content of the fuel was fixed and the impact of NO<sub>x</sub> emissions on the O<sub>2</sub> ratio (O<sub>2</sub>/fuel equivalence ratio) was investigated. The calculated results for the temperature field, velocity field, and NOx concentration at the furnace outlet agree with the IFRF experimental results. As the N<sub>2</sub> content in the oxidizer and fuel increased, the NO<sub>x</sub> concentration also increased. NO<sub>x</sub> emissions were much higher with a larger amount of N<sub>2</sub> in the fuel than in the oxidizer. With fixed N<sub>2</sub> content in the fuel, NO<sub>x</sub> concentration tended to increase as the O<sub>2</sub> ratio increased. As the N<sub>2</sub> content in the fuel increased, the tendency of the NO<sub>x</sub> concentration to increase with the O<sub>2</sub> ratio became more evident. This study emphasizes the importance of minimizing the N<sub>2</sub> content in both the fuel and oxidizer during NG-O<sub>2</sub> combustion, and suggests that NO<sub>x</sub> emissions can be effectively controlled by adjusting the oxygen ratio when N<sub>2</sub> is present.</div></div>","PeriodicalId":9658,"journal":{"name":"Case Studies in Thermal Engineering","volume":"68 ","pages":"Article 105868"},"PeriodicalIF":6.4000,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Case Studies in Thermal Engineering","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2214157X25001285","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"THERMODYNAMICS","Score":null,"Total":0}
引用次数: 0
Abstract
This study aims to understand the NOx emission characteristics during pure oxygen (O2) combustion of natural gas (NG) and to provide design data for application in forging furnaces. We numerically investigated the sensitivity of NOx emissions to an up to 10 % increase in nitrogen (N2) content of the fuel and oxidizer. According to the impact analysis, the two cases have a more adverse effect on NOx emissions. The numerical model established in this study was verified using experimental results obtained by the International Flame Research Foundation (IFRF). In addition, the N2 content of the fuel was fixed and the impact of NOx emissions on the O2 ratio (O2/fuel equivalence ratio) was investigated. The calculated results for the temperature field, velocity field, and NOx concentration at the furnace outlet agree with the IFRF experimental results. As the N2 content in the oxidizer and fuel increased, the NOx concentration also increased. NOx emissions were much higher with a larger amount of N2 in the fuel than in the oxidizer. With fixed N2 content in the fuel, NOx concentration tended to increase as the O2 ratio increased. As the N2 content in the fuel increased, the tendency of the NOx concentration to increase with the O2 ratio became more evident. This study emphasizes the importance of minimizing the N2 content in both the fuel and oxidizer during NG-O2 combustion, and suggests that NOx emissions can be effectively controlled by adjusting the oxygen ratio when N2 is present.
期刊介绍:
Case Studies in Thermal Engineering provides a forum for the rapid publication of short, structured Case Studies in Thermal Engineering and related Short Communications. It provides an essential compendium of case studies for researchers and practitioners in the field of thermal engineering and others who are interested in aspects of thermal engineering cases that could affect other engineering processes. The journal not only publishes new and novel case studies, but also provides a forum for the publication of high quality descriptions of classic thermal engineering problems. The scope of the journal includes case studies of thermal engineering problems in components, devices and systems using existing experimental and numerical techniques in the areas of mechanical, aerospace, chemical, medical, thermal management for electronics, heat exchangers, regeneration, solar thermal energy, thermal storage, building energy conservation, and power generation. Case studies of thermal problems in other areas will also be considered.