Xiliang LIU , Hao CHEN , Yang LI , Yangwen ZHU , Haiying LIAO , Qingmin ZHAO , Xianmin ZHOU , Hongbo ZENG
{"title":"Oil production characteristics and CO2 storage mechanisms of CO2 flooding in ultra-low permeability sandstone oil reservoirs","authors":"Xiliang LIU , Hao CHEN , Yang LI , Yangwen ZHU , Haiying LIAO , Qingmin ZHAO , Xianmin ZHOU , Hongbo ZENG","doi":"10.1016/S1876-3804(25)60014-0","DOIUrl":null,"url":null,"abstract":"<div><div>Using the ultra-low permeability reservoirs in the L block of the Jiangsu oilfield as an example, a series of experiments, including slim tube displacement experiments of CO<sub>2</sub>-oil system, injection capacity experiments, and high-temperature, high-pressure online nuclear magnetic resonance (NMR) displacement experiments, are conducted to reveal the oil/gas mass transfer pattern and oil production mechanisms during CO<sub>2</sub> flooding in ultra-low permeability reservoirs. The impacts of CO<sub>2</sub> storage pore range and miscibility on oil production and CO<sub>2</sub> storage characteristics during CO<sub>2</sub> flooding are clarified. The CO<sub>2</sub> flooding process is divided into three stages: oil displacement stage by CO<sub>2</sub>, CO<sub>2</sub> breakthrough stage, CO<sub>2</sub> extraction stage. Crude oil expansion and viscosity reduction are the main mechanisms for improving recovery in the CO<sub>2</sub> displacement stage. After CO<sub>2</sub> breakthrough, the extraction of light components from the crude oil further enhances oil recovery. During CO<sub>2</sub> flooding, the contribution of crude oil in large pores to the enhanced recovery exceeds 46%, while crude oil in medium pores serves as a reserve for incremental recovery. After CO<sub>2</sub> breakthrough, a small portion of the crude oil is extracted and carried into nano-scale pores by CO<sub>2</sub>, becoming residual oil that is hard to recover. As the miscibility increases, the CO<sub>2</sub> front moves more stably and sweeps a larger area, leading to increased CO<sub>2</sub> storage range and volume. The CO<sub>2</sub> full-storage stage contributes the most to the overall CO<sub>2</sub> storage volume. In the CO<sub>2</sub> escape stage, the storage mechanism involves partial in-situ storage of crude oil within the initial pore range and the CO<sub>2</sub> carrying crude oil into smaller pores to increase the volume of stored CO<sub>2</sub>. In the CO<sub>2</sub> leakage stage, as crude oil is produced, a significant amount of CO<sub>2</sub> leaks out, causing a sharp decline in the storage efficiency.</div></div>","PeriodicalId":67426,"journal":{"name":"Petroleum Exploration and Development","volume":"52 1","pages":"Pages 196-207"},"PeriodicalIF":7.0000,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Petroleum Exploration and Development","FirstCategoryId":"1087","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1876380425600140","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
Abstract
Using the ultra-low permeability reservoirs in the L block of the Jiangsu oilfield as an example, a series of experiments, including slim tube displacement experiments of CO2-oil system, injection capacity experiments, and high-temperature, high-pressure online nuclear magnetic resonance (NMR) displacement experiments, are conducted to reveal the oil/gas mass transfer pattern and oil production mechanisms during CO2 flooding in ultra-low permeability reservoirs. The impacts of CO2 storage pore range and miscibility on oil production and CO2 storage characteristics during CO2 flooding are clarified. The CO2 flooding process is divided into three stages: oil displacement stage by CO2, CO2 breakthrough stage, CO2 extraction stage. Crude oil expansion and viscosity reduction are the main mechanisms for improving recovery in the CO2 displacement stage. After CO2 breakthrough, the extraction of light components from the crude oil further enhances oil recovery. During CO2 flooding, the contribution of crude oil in large pores to the enhanced recovery exceeds 46%, while crude oil in medium pores serves as a reserve for incremental recovery. After CO2 breakthrough, a small portion of the crude oil is extracted and carried into nano-scale pores by CO2, becoming residual oil that is hard to recover. As the miscibility increases, the CO2 front moves more stably and sweeps a larger area, leading to increased CO2 storage range and volume. The CO2 full-storage stage contributes the most to the overall CO2 storage volume. In the CO2 escape stage, the storage mechanism involves partial in-situ storage of crude oil within the initial pore range and the CO2 carrying crude oil into smaller pores to increase the volume of stored CO2. In the CO2 leakage stage, as crude oil is produced, a significant amount of CO2 leaks out, causing a sharp decline in the storage efficiency.