Waleed N. Al-DARKAZALI , Sara S. HAMOOD , Nassim ALDAHER , Nazar Sattar HARBI
{"title":"Studying the effect of using metal oxide nanofluids on the performance of a single-tube heat exchanger","authors":"Waleed N. Al-DARKAZALI , Sara S. HAMOOD , Nassim ALDAHER , Nazar Sattar HARBI","doi":"10.1016/j.cjac.2025.100497","DOIUrl":null,"url":null,"abstract":"<div><div>The preparation of aluminum oxide from nanofluid (Al<sub>2</sub>O<sub>3</sub>/H<sub>2</sub>O) in three different concentrations using a two-step method was achieved by using an atomic force microscopy (AFM). The AFM images showed that the nanoparticles took on a spherical shape with a range of average diameters and density within the range of 45–55 nm.</div><div>Polyacrylamide (PAAM) was used as a dispersion and suspension agent for aluminum oxide nanoparticles in distilled water at various concentrations (250, 500, 750, 1000) ppm during preparation, followed by determination of the polymer ratio for each sample during preparation, stability assessment by ultraviolet-visible (UV-Vis) spectrophotometer in the wavelength field (200–700) nm for 10 days, and analysis of sample Alumina nanoparticles by dispersion and suspension agent by high-pressure polymers tended M25 resulting in the highest concentrations of the given concentration. By increasing the PAAM concentration, the dispersion and stability of Al<sub>2</sub>O<sub>3</sub> nanoparticles in distilled water appear to be improved, and concentrations of 0.25% seemed to be more evenly dispersed and stable over time, with minor sedimentation compared to (0.1%, 0.05%) vol concentrations, where the absorbance peak decreased by 5.5% despite the increase in size of Al<sub>2</sub>O<sub>3</sub> nanoparticles and their aggregations, while the absorbance peak in the previous concentrations decreased by (14.2% and 8.8%), respectively of the two previous concentrations of Al<sub>2</sub>O<sub>3</sub>.</div><div>The study of PAAM polymers demonstrated that their rheological properties were not Newtonian, owing to a higher concentration of the polymer, resulting in viscosity results that resembled non-Newtonian polysaccharides.</div></div>","PeriodicalId":277,"journal":{"name":"Chinese Journal of Analytical Chemistry","volume":"53 3","pages":"Article 100497"},"PeriodicalIF":1.2000,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chinese Journal of Analytical Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1872204025000076","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The preparation of aluminum oxide from nanofluid (Al2O3/H2O) in three different concentrations using a two-step method was achieved by using an atomic force microscopy (AFM). The AFM images showed that the nanoparticles took on a spherical shape with a range of average diameters and density within the range of 45–55 nm.
Polyacrylamide (PAAM) was used as a dispersion and suspension agent for aluminum oxide nanoparticles in distilled water at various concentrations (250, 500, 750, 1000) ppm during preparation, followed by determination of the polymer ratio for each sample during preparation, stability assessment by ultraviolet-visible (UV-Vis) spectrophotometer in the wavelength field (200–700) nm for 10 days, and analysis of sample Alumina nanoparticles by dispersion and suspension agent by high-pressure polymers tended M25 resulting in the highest concentrations of the given concentration. By increasing the PAAM concentration, the dispersion and stability of Al2O3 nanoparticles in distilled water appear to be improved, and concentrations of 0.25% seemed to be more evenly dispersed and stable over time, with minor sedimentation compared to (0.1%, 0.05%) vol concentrations, where the absorbance peak decreased by 5.5% despite the increase in size of Al2O3 nanoparticles and their aggregations, while the absorbance peak in the previous concentrations decreased by (14.2% and 8.8%), respectively of the two previous concentrations of Al2O3.
The study of PAAM polymers demonstrated that their rheological properties were not Newtonian, owing to a higher concentration of the polymer, resulting in viscosity results that resembled non-Newtonian polysaccharides.
期刊介绍:
Chinese Journal of Analytical Chemistry(CJAC) is an academic journal of analytical chemistry established in 1972 and sponsored by the Chinese Chemical Society and Changchun Institute of Applied Chemistry, Chinese Academy of Sciences. Its objectives are to report the original scientific research achievements and review the recent development of analytical chemistry in all areas. The journal sets up 5 columns including Research Papers, Research Notes, Experimental Technique and Instrument, Review and Progress and Summary Accounts. The journal published monthly in Chinese language. A detailed abstract, keywords and the titles of figures and tables are provided in English, except column of Summary Accounts. Prof. Wang Erkang, an outstanding analytical chemist, academician of Chinese Academy of Sciences & Third World Academy of Sciences, holds the post of the Editor-in-chief.