pts-Type Aluminoborate with Nonlinear Optical Properties

IF 4.3 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Inorganic Chemistry Pub Date : 2025-02-20 DOI:10.1021/acs.inorgchem.4c05459

Lan Wang, Juan Chen, Guo-Yu Yang

引用次数: 0

Abstract

A noncentric 3D aluminoborate (ABO), NaCs₂[AlB₅O₁₀]·HCOO·H₂O (1), has been constructed through the solvothermal technique. The framework of 1 is formed by the alternation of AlO₄ tetrahedra and B₅O₁₀ clusters, featuring 7 types of channels. 1 belongs to the “10,10-linkage”, which features an unprecedented pts topology in the ABO field. The measurement of second-harmonic generation (SHG) shows that 1 displays an SHG value roughly 1.1 times that of KH₂PO₄ (KDP). The UV–vis diffuse reflectance spectrum suggests potential applications for 1 in the deep ultraviolet (DUV) field.

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来源期刊

Inorganic Chemistry 化学-无机化学与核化学

CiteScore

7.60

自引率

13.00%

发文量

1960

审稿时长

1.9 months

期刊介绍： Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.