Synthesis, Crystal Structure, and Elementary Electrical Characterization of Quasi-One-Dimensional TiSe3

IF 4.3 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Inorganic Chemistry Pub Date : 2025-02-20 DOI:10.1021/acs.inorgchem.4c05396

Danrui Ni, Teresa Lee, Stephen Zhang, Xianghan Xu, R. J. Cava

引用次数: 0

Abstract

The solid-state synthesis at an applied pressure of 6 GPa, crystal structure, and elementary electronic properties of the previously unreported compound TiSe₃ are described. The crystal structure, which is based on 1D chains of Ti–Se triangular prisms that are coupled to each other, with two-thirds of the Se involved in a Se–Se pair, is similar to that of TiS₃. Unlike the trisulfide, the triselenide is only made under pressure at temperatures between 800 and 900 °C. The material is semiconducting and weakly diamagnetic.

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来源期刊

Inorganic Chemistry 化学-无机化学与核化学

CiteScore

7.60

自引率

13.00%

发文量

1960

审稿时长

1.9 months

期刊介绍： Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.