{"title":"Innovative use of Fe2O3-modified TiO2 coated PE foam for extending the freshness of Barracuda mango","authors":"Peerawas Kongsong , Tada Boonyalak , Waritha Jantaporn , Mahamasuhaimi Masae","doi":"10.1016/j.jphotochem.2025.116341","DOIUrl":null,"url":null,"abstract":"<div><div>Preserving fruits after harvest has been challenging, especially Barracuda mangoes because they are highly perishable produce. This paper takes a novel approach incorporating the use of Fe<sub>2</sub>O<sub>3</sub>-modified TiO<sub>2</sub> (Fe<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub>) coated polyethylene (PE) foam fruit nets to enhance the shelf life of those mangoes. Various aspects of the study include identifying characterization techniques used in Fe<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub>. The synthesized TiO<sub>2</sub> particles were analyzed for particle size distribution and size to get the optimum properties for the coating effectiveness. The study examined the methylene blue (MB) degradation mechanism. A UV–Vis spectrometer was used to determine the optical properties of the Fe<sub>2</sub>O<sub>3</sub>-modified TiO<sub>2</sub>, SEM was used to analyze the surface of the coated PE foam nets, indicating even distribution and strong adhesion of the TiO<sub>2</sub> particles. An energy-dispersive X-ray spectroscopy (EDS) test was performed together with an SEM analysis to determine the content of conductive elements and to ensure that Fe was modified into the TiO<sub>2</sub> structure. This research confirms that Fe<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> coatings effectively increase mangoes’ shelf life through their negative impact on microbial growth and the slowing of other ripening processes. Fe<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> at the maximum concentration of 1.0 % w/v further showed a considerable shelf-life extension of 130.23 % to the control sample without coating. Experimental results revealed that the Fe-modified TiO<sub>2</sub> materials performed better in MB degradation tests than unmodified TiO<sub>2</sub>. The study also established that the photocatalytic effect of TiO<sub>2</sub> is improved upon Fe modified because the bandgap is also reduced hence improved antimicrobial efficacy when exposed for a short time under fluorescent light. As a contribution to solving the problem of food waste and disease control in technology after the harvest, this study has identified the possibility of using Fe<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub> coatings. Further work should also concentrate on enhancing the use of coating to fit the requirements for large-scale application of this technology.</div></div>","PeriodicalId":16782,"journal":{"name":"Journal of Photochemistry and Photobiology A-chemistry","volume":"465 ","pages":"Article 116341"},"PeriodicalIF":4.1000,"publicationDate":"2025-02-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Photochemistry and Photobiology A-chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1010603025000814","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Preserving fruits after harvest has been challenging, especially Barracuda mangoes because they are highly perishable produce. This paper takes a novel approach incorporating the use of Fe2O3-modified TiO2 (Fe2O3/TiO2) coated polyethylene (PE) foam fruit nets to enhance the shelf life of those mangoes. Various aspects of the study include identifying characterization techniques used in Fe2O3/TiO2. The synthesized TiO2 particles were analyzed for particle size distribution and size to get the optimum properties for the coating effectiveness. The study examined the methylene blue (MB) degradation mechanism. A UV–Vis spectrometer was used to determine the optical properties of the Fe2O3-modified TiO2, SEM was used to analyze the surface of the coated PE foam nets, indicating even distribution and strong adhesion of the TiO2 particles. An energy-dispersive X-ray spectroscopy (EDS) test was performed together with an SEM analysis to determine the content of conductive elements and to ensure that Fe was modified into the TiO2 structure. This research confirms that Fe2O3/TiO2 coatings effectively increase mangoes’ shelf life through their negative impact on microbial growth and the slowing of other ripening processes. Fe2O3/TiO2 at the maximum concentration of 1.0 % w/v further showed a considerable shelf-life extension of 130.23 % to the control sample without coating. Experimental results revealed that the Fe-modified TiO2 materials performed better in MB degradation tests than unmodified TiO2. The study also established that the photocatalytic effect of TiO2 is improved upon Fe modified because the bandgap is also reduced hence improved antimicrobial efficacy when exposed for a short time under fluorescent light. As a contribution to solving the problem of food waste and disease control in technology after the harvest, this study has identified the possibility of using Fe2O3/TiO2 coatings. Further work should also concentrate on enhancing the use of coating to fit the requirements for large-scale application of this technology.
期刊介绍:
JPPA publishes the results of fundamental studies on all aspects of chemical phenomena induced by interactions between light and molecules/matter of all kinds.
All systems capable of being described at the molecular or integrated multimolecular level are appropriate for the journal. This includes all molecular chemical species as well as biomolecular, supramolecular, polymer and other macromolecular systems, as well as solid state photochemistry. In addition, the journal publishes studies of semiconductor and other photoactive organic and inorganic materials, photocatalysis (organic, inorganic, supramolecular and superconductor).
The scope includes condensed and gas phase photochemistry, as well as synchrotron radiation chemistry. A broad range of processes and techniques in photochemistry are covered such as light induced energy, electron and proton transfer; nonlinear photochemical behavior; mechanistic investigation of photochemical reactions and identification of the products of photochemical reactions; quantum yield determinations and measurements of rate constants for primary and secondary photochemical processes; steady-state and time-resolved emission, ultrafast spectroscopic methods, single molecule spectroscopy, time resolved X-ray diffraction, luminescence microscopy, and scattering spectroscopy applied to photochemistry. Papers in emerging and applied areas such as luminescent sensors, electroluminescence, solar energy conversion, atmospheric photochemistry, environmental remediation, and related photocatalytic chemistry are also welcome.