[Seasonal Pollution Characteristics and Source Apportionment of Atmospheric VOCs in Central Urban Area of Chongqing].

Q2 Environmental Science
Jia Yao, Zhen-Liang Li, Mu-Lan Chen, Ling Li, Qin Xu, Wei-Kai Fang, Chao Peng, Chong-Zhi Zhai, Feng-Wen Wang, Pei-Li Lu
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Abstract

The long-term seasonal pollution characteristics, environmental effects, and sources of atmospheric volatile organic compounds (VOCs) were investigated based on the one-year (06/2021-05/2022) online observation data of VOCs in the central urban area of Chongqing. The results showed that during the observation period, the mean value of φ(VOCs) was 31.5×10-9, of which alkane accounted for the highest proportion (39.6%), followed by oxygenated VOCs (OVOCs) (15.6%), halogenated hydrocarbons (13.9%), aromatic hydrocarbons (11.6%), olefin (10.5%), and alkyne (8.3%). In terms of time, the volume fraction changed to winter (35.7×10-9) > autumn (32.5×10-9) > summer (31.3×10-9) > spring (27.6×10-9). In summer, the highest contribution of aromatic hydrocarbons to ozone generation was observed in 1,2,4-tritylene, toluene, and m/p-xylene species with higher ozone generation potential (OFP). In winter, the contribution of aromatic hydrocarbons to the formation potential of secondary organic aerosols (SOA) was as high as 96%, and toluene and m/p-xylene were the main contributing species to the formation potential of SOA. The main sources of VOCs in summer were motor vehicle emissions (30.9%), industrial emissions (21.2%), and solvent use sources (18.6%), and the main sources in winter were motor vehicle exhaust (35.8%), combustion sources (30.9%), and industrial sources (20.6%). The contribution of combustion sources to VOCs in winter (30.9%) was significantly higher than that in summer (17.4%).

重庆中心城区大气VOCs季节污染特征及来源解析[j]。
基于重庆市中心城区1年(2021年6月- 2022年5月)挥发性有机物(VOCs)在线观测数据,研究了重庆市中心城区大气挥发性有机物(VOCs)的长期季节性污染特征、环境效应及来源。结果表明:观测期内,φ(VOCs)均值为31.5×10-9,其中烷烃所占比例最高(39.6%),其次为含氧VOCs (OVOCs)(15.6%)、卤化烃(13.9%)、芳烃(11.6%)、烯烃(10.5%)、炔(8.3%)。在时间上,体积分数变为冬季(35.7×10-9) >;秋季(32.5×10-9) >;夏天(31.3×10-9) >;春天(27.6×9)。在夏季,臭氧生成潜力(OFP)较高的1,2,4-三甲苯、甲苯和间/对二甲苯中芳烃对臭氧生成的贡献最大。冬季,芳烃对次生有机气溶胶(SOA)形成势的贡献高达96%,甲苯和间/对二甲苯是次生有机气溶胶形成势的主要贡献物质。夏季VOCs主要来源为机动车排放(30.9%)、工业排放(21.2%)和溶剂使用(18.6%),冬季主要来源为机动车尾气(35.8%)、燃烧源(30.9%)和工业源(20.6%)。冬季燃烧源对VOCs的贡献率(30.9%)显著高于夏季(17.4%)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
环境科学
环境科学 Environmental Science-Environmental Science (all)
CiteScore
4.40
自引率
0.00%
发文量
15329
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