[Seasonal Pollution Characteristics and Source Apportionment of Atmospheric VOCs in Central Urban Area of Chongqing].

Q2 Environmental Science
Jia Yao, Zhen-Liang Li, Mu-Lan Chen, Ling Li, Qin Xu, Wei-Kai Fang, Chao Peng, Chong-Zhi Zhai, Feng-Wen Wang, Pei-Li Lu
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引用次数: 0

Abstract

The long-term seasonal pollution characteristics, environmental effects, and sources of atmospheric volatile organic compounds (VOCs) were investigated based on the one-year (06/2021-05/2022) online observation data of VOCs in the central urban area of Chongqing. The results showed that during the observation period, the mean value of φ(VOCs) was 31.5×10-9, of which alkane accounted for the highest proportion (39.6%), followed by oxygenated VOCs (OVOCs) (15.6%), halogenated hydrocarbons (13.9%), aromatic hydrocarbons (11.6%), olefin (10.5%), and alkyne (8.3%). In terms of time, the volume fraction changed to winter (35.7×10-9) > autumn (32.5×10-9) > summer (31.3×10-9) > spring (27.6×10-9). In summer, the highest contribution of aromatic hydrocarbons to ozone generation was observed in 1,2,4-tritylene, toluene, and m/p-xylene species with higher ozone generation potential (OFP). In winter, the contribution of aromatic hydrocarbons to the formation potential of secondary organic aerosols (SOA) was as high as 96%, and toluene and m/p-xylene were the main contributing species to the formation potential of SOA. The main sources of VOCs in summer were motor vehicle emissions (30.9%), industrial emissions (21.2%), and solvent use sources (18.6%), and the main sources in winter were motor vehicle exhaust (35.8%), combustion sources (30.9%), and industrial sources (20.6%). The contribution of combustion sources to VOCs in winter (30.9%) was significantly higher than that in summer (17.4%).

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环境科学
环境科学 Environmental Science-Environmental Science (all)
CiteScore
4.40
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0.00%
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15329
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