{"title":"Bio-MOF-11 Derived Amorphous Cobalt Hollow Nanospheres to Access Bioactive Quinazolinone Scaffolds and Aromatic Amines","authors":"Natarajan Anbuselvan, Selvam Sivaprakash, Sivakumar Pooja, Kesavan Nithya, Devarajan Suresh, Arlin Jose Amali","doi":"10.1002/cctc.202401536","DOIUrl":null,"url":null,"abstract":"<p>A facile synthetic strategy is reported to afford bioactive quinazolinones and aromatic amines by employing amorphous cobalt hollow nanospheres (Co HNS) derived from a Bio-MOF, cobalt adeninate, as a catalyst. Modulated electron states of the amorphous cobalt with a high concentration of surficial active sites and Co–N sites enhance the intrinsic catalytic activity while the support, activated carbon, facilitates the formation of hollow structure.</p>","PeriodicalId":141,"journal":{"name":"ChemCatChem","volume":"17 4","pages":""},"PeriodicalIF":3.8000,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemCatChem","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/cctc.202401536","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
A facile synthetic strategy is reported to afford bioactive quinazolinones and aromatic amines by employing amorphous cobalt hollow nanospheres (Co HNS) derived from a Bio-MOF, cobalt adeninate, as a catalyst. Modulated electron states of the amorphous cobalt with a high concentration of surficial active sites and Co–N sites enhance the intrinsic catalytic activity while the support, activated carbon, facilitates the formation of hollow structure.
期刊介绍:
With an impact factor of 4.495 (2018), ChemCatChem is one of the premier journals in the field of catalysis. The journal provides primary research papers and critical secondary information on heterogeneous, homogeneous and bio- and nanocatalysis. The journal is well placed to strengthen cross-communication within between these communities. Its authors and readers come from academia, the chemical industry, and government laboratories across the world. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies, and is supported by the German Catalysis Society.