Siloxyflavylium Triflates as Organic Photocatalysts

IF 3.8 3区化学 Q2 CHEMISTRY, PHYSICAL

ChemCatChem Pub Date : 2024-11-20 DOI:10.1002/cctc.202401552

Anitha Alanthadka, Lillian Carleu, August Vitarbo, Kalen Laybourn, Ronald L. Grimm, Anita E. Mattson

引用次数: 0

Abstract

Photocatalysis is a promising tool for complex molecule construction. Inspired by the potential of photocatalysis, the investigations herein describe the development of siloxyflavium triflates as a new family of organic photocatalysts for synthetic chemistry. In this report, the application of siloxyflavium triflate photocatalysis is demonstrated in the α-C-H activation of ethers in the presence of chromenones to generate valuable, biologically relevant C(sp³)-C(sp³) linkages. The scope of the bond-forming event is demonstrated with 20 substrates.

Abstract Image

查看原文本刊更多论文

求助全文

约1分钟内获得全文求助全文

来源期刊

ChemCatChem 化学-物理化学

CiteScore

8.10

自引率

4.40%

发文量

511

审稿时长

1.3 months

期刊介绍： With an impact factor of 4.495 (2018), ChemCatChem is one of the premier journals in the field of catalysis. The journal provides primary research papers and critical secondary information on heterogeneous, homogeneous and bio- and nanocatalysis. The journal is well placed to strengthen cross-communication within between these communities. Its authors and readers come from academia, the chemical industry, and government laboratories across the world. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies, and is supported by the German Catalysis Society.