Visible-Light-Mediated C−H Difluoroalkylation of (Hetero)arenes: A New Application of Vibration-Induced-Emission Molecule 9,14-Diphenyl-dihydrodibenzo[a,c]phenazine

IF 3.8 3区化学 Q2 CHEMISTRY, PHYSICAL

ChemCatChem Pub Date : 2024-11-23 DOI:10.1002/cctc.202401699

Chengxi Zhang, Zhiyun Zhang, Yifeng Chen

引用次数: 0

Abstract

Herein, we report a vibration-induced emission molecule, 9,14-diphenyl-dihydrodibenzo[a,c]phenazines (DPAC), compound-catalyzed C−H difluoroalkylation of (hetero)arenes under visible light conditions. This method demonstrates the promising potential of vibration-induced-emission (VIE) molecules in photocatalysis and facilitates a metal-free synthetic approach for difluoroalkyl (hetero)arenes with broad substrate scope and functional group tolerance.

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来源期刊

ChemCatChem 化学-物理化学

CiteScore

8.10

自引率

4.40%

发文量

511

审稿时长

1.3 months

期刊介绍： With an impact factor of 4.495 (2018), ChemCatChem is one of the premier journals in the field of catalysis. The journal provides primary research papers and critical secondary information on heterogeneous, homogeneous and bio- and nanocatalysis. The journal is well placed to strengthen cross-communication within between these communities. Its authors and readers come from academia, the chemical industry, and government laboratories across the world. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies, and is supported by the German Catalysis Society.