M. N. Smirnova, M. A. Kop’eva, G. D. Nipan, G. E. Nikiforova, E. V. Tekshina, A. A. Arkhipenko
{"title":"Solid Solution in Pseudobinary System Ba2YMoO6–[Ba2YCuO5]","authors":"M. N. Smirnova, M. A. Kop’eva, G. D. Nipan, G. E. Nikiforova, E. V. Tekshina, A. A. Arkhipenko","doi":"10.1134/S0036023624601466","DOIUrl":null,"url":null,"abstract":"<p>Polycrystalline samples of the pseudobinary system Ba<sub>2</sub>YMoO<sub>6</sub>–[Ba<sub>2</sub>YCuO<sub>5</sub>] were synthesized using the gel combustion method. The obtained samples were investigated using X-ray diffraction and photoluminescence spectroscopy. The substitution of Mo with Cu led to the stabilization of cubic phases <i>Fm</i>3̅<i>m</i> and <i>F</i>4̅3<i>m</i> of the solid solution Ba<sub>2</sub>YMo<sub>1 –</sub> <sub><i>x</i></sub>Cu<sub><i>x</i></sub>O<sub>6 – δ</sub> (0 ≤ <i>x</i> ≤ 0.5) in air.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"69 10","pages":"1540 - 1543"},"PeriodicalIF":1.8000,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036023624601466","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Polycrystalline samples of the pseudobinary system Ba2YMoO6–[Ba2YCuO5] were synthesized using the gel combustion method. The obtained samples were investigated using X-ray diffraction and photoluminescence spectroscopy. The substitution of Mo with Cu led to the stabilization of cubic phases Fm3̅m and F4̅3m of the solid solution Ba2YMo1 –xCuxO6 – δ (0 ≤ x ≤ 0.5) in air.
期刊介绍:
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.