Yu-Qi Gao, Zhong-Wu An, Shao-Min Xu and Min-Xia Yao*,
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引用次数: 0
Abstract
By using chloranilate anions to react with 3d complexes ([M(L)(H2O)2], H2L = 1,3-propanediylbis(2-iminomethylene-6-methoxy-phenol)) and 4f ions, a series of phenoxo- and chloranilate-bridged zigzag M2Ln2 clusters (M = Ni, Ln = Gd, Tb, Dy, Ho, and Eu for 1–5, respectively; M = Zn, Ln = Gd, Tb, Dy, Ho, and Eu for 6–10, respectively) have been obtained and structurally characterized. They are rare chloranilate-bridged 3d–4f heterometallic complexes. All of the Tb and Eu derivatives exhibit characteristic emission peaks of the corresponding LnIII ion. Magnetic studies reveal that two Dy derivatives display field-induced single-molecule magnet properties with energy barriers of 7.44 K for 3 and 50.64 K for 8.
期刊介绍：
The aim of Crystal Growth & Design is to stimulate crossfertilization of knowledge among scientists and engineers working in the fields of crystal growth, crystal engineering, and the industrial application of crystalline materials.
Crystal Growth & Design publishes theoretical and experimental studies of the physical, chemical, and biological phenomena and processes related to the design, growth, and application of crystalline materials. Synergistic approaches originating from different disciplines and technologies and integrating the fields of crystal growth, crystal engineering, intermolecular interactions, and industrial application are encouraged.
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