Huilin Xie, Kaibin Zhong, Shihao Niu, Xiaoxu Li, Zexu Hu, Guang Xiao, Prof. Yifu Huang, Prof. Hongjie Zhang, Prof. Yuan Liu, Prof. Hefeng Zhang, Prof. Qiuquan Cai
{"title":"Rücktitelbild: Air-Mediated Biomimetic Synthesis of Polyhydroxyalkanoate with C4 Diol (Angew. Chem. 8/2025)","authors":"Huilin Xie, Kaibin Zhong, Shihao Niu, Xiaoxu Li, Zexu Hu, Guang Xiao, Prof. Yifu Huang, Prof. Hongjie Zhang, Prof. Yuan Liu, Prof. Hefeng Zhang, Prof. Qiuquan Cai","doi":"10.1002/ange.202502402","DOIUrl":null,"url":null,"abstract":"<p>A strategy for the biomimetic synthesis of polyhydroxyalkanoates (PHA) using C4 diol and air, catalyzed by a synergistic catalyst, was presented by Qiuquan Cai and co-workers in their Research Article (e202417660). The resulting PHA can reversibly convert back to a small-molecule monomer in the form of a five-membered ring, demonstrating excellent ecological sustainability. This study highlights the potential for large-scale synthesis of high-value PHAs from diverse non-grain-based diols.\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 8","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202502402","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202502402","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
A strategy for the biomimetic synthesis of polyhydroxyalkanoates (PHA) using C4 diol and air, catalyzed by a synergistic catalyst, was presented by Qiuquan Cai and co-workers in their Research Article (e202417660). The resulting PHA can reversibly convert back to a small-molecule monomer in the form of a five-membered ring, demonstrating excellent ecological sustainability. This study highlights the potential for large-scale synthesis of high-value PHAs from diverse non-grain-based diols.