Rücktitelbild: Air-Mediated Biomimetic Synthesis of Polyhydroxyalkanoate with C4 Diol (Angew. Chem. 8/2025)

Huilin Xie, Kaibin Zhong, Shihao Niu, Xiaoxu Li, Zexu Hu, Guang Xiao, Prof. Yifu Huang, Prof. Hongjie Zhang, Prof. Yuan Liu, Prof. Hefeng Zhang, Prof. Qiuquan Cai
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Abstract

A strategy for the biomimetic synthesis of polyhydroxyalkanoates (PHA) using C4 diol and air, catalyzed by a synergistic catalyst, was presented by Qiuquan Cai and co-workers in their Research Article (e202417660). The resulting PHA can reversibly convert back to a small-molecule monomer in the form of a five-membered ring, demonstrating excellent ecological sustainability. This study highlights the potential for large-scale synthesis of high-value PHAs from diverse non-grain-based diols.

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来源期刊
Angewandte Chemie
Angewandte Chemie 化学科学, 有机化学, 有机合成
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