Achieving 2.1% Efficiency in Alpha-Voltaic Cell Based on Silicon Carbide Transducer

IF 13 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Runlong Gao, Wuying Ma, Pengying Wan, Ao Liu, Xiao Ouyang, Xue Du, Qiantao Lei, Qi Deng, Linyue Liu, Xiaoping Ouyang
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Abstract

Alpha-voltaic cell is a type of micro nuclear battery that provides several decades of reliable power in the nanowatt to microwatt range, supplying for special applications where traditional chemical batteries or solar cells are difficult to operate. However, the power conversion efficiency of the alpha-voltaic cells reported are still far behind the theoretical limit, making the development of alpha-voltaic cell challenging. Developing advanced semiconductor transducers with higher efficiency in converting the energy of alpha particles into electric energy is proving to be necessary for realizing high-power conversion efficiency. Herein, we propose an alpha-voltaic cell based on SiC PIN transducer that includes a sensitive region with an area of 1 cm2, a width of 51.2 μm, and a charge collection efficiency of 95.6% at 0 V bias. We find that optimizing the unintentional doping concentration and crystal quality of the SiC epitaxial layer can significantly increase the absorption and utilization of the energy of alpha particles, resulting in a 2.4-fold enhancement in power conversion efficiency compared with that of the previous study. Electrical properties of the SiC alpha-voltaic cell are measured using an He-ion accelerator as the equivalent α-radioisotopes, with the best power conversion efficiency of 2.10% and maximum output power density of 406.66 nW cm−2 is obtained. Our research makes a big leap in SiC alpha-voltaic cell, bridging the gap between micro nuclear batteries and practical applications in micro-electromechanical systems, micro aerial vehicles, and tiny satellites.

Abstract Image

基于碳化硅换能器的阿尔法光伏电池实现 2.1% 的效率
阿尔法伏打电池是一种微型核电池,可以提供几十年在纳瓦到微瓦范围内的可靠电力,用于传统化学电池或太阳能电池难以操作的特殊应用。然而,目前报道的α -光伏电池的功率转换效率仍然远远落后于理论极限,这使得α -光伏电池的发展具有挑战性。开发先进的半导体换能器,将α粒子的能量转换为电能的效率更高,是实现高功率转换效率的必要条件。本文提出了一种基于SiC PIN传感器的α -光伏电池,其敏感区面积为1 cm2,宽度为51.2 μm,在0 V偏置下电荷收集效率为95.6%。我们发现,优化SiC外延层的无意掺杂浓度和晶体质量,可以显著提高α粒子对能量的吸收和利用,使功率转换效率比之前的研究提高2.4倍。采用氦离子加速器作为等效α-放射性同位素,测量了SiC α-光伏电池的电学性能,获得了最佳功率转换效率为2.10%,最大输出功率密度为406.66 nW cm−2。我们的研究在碳化硅α光伏电池方面取得了重大飞跃,弥合了微型核电池与微机电系统、微型飞行器和微型卫星实际应用之间的差距。
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来源期刊
Energy & Environmental Materials
Energy & Environmental Materials MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
17.60
自引率
6.00%
发文量
66
期刊介绍: Energy & Environmental Materials (EEM) is an international journal published by Zhengzhou University in collaboration with John Wiley & Sons, Inc. The journal aims to publish high quality research related to materials for energy harvesting, conversion, storage, and transport, as well as for creating a cleaner environment. EEM welcomes research work of significant general interest that has a high impact on society-relevant technological advances. The scope of the journal is intentionally broad, recognizing the complexity of issues and challenges related to energy and environmental materials. Therefore, interdisciplinary work across basic science and engineering disciplines is particularly encouraged. The areas covered by the journal include, but are not limited to, materials and composites for photovoltaics and photoelectrochemistry, bioprocessing, batteries, fuel cells, supercapacitors, clean air, and devices with multifunctionality. The readership of the journal includes chemical, physical, biological, materials, and environmental scientists and engineers from academia, industry, and policy-making.
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