Study on freeze-thaw resistance and Na+ leaching characteristics of red mud-fly ash-phosphogypsum multiple solid waste road base material

Abstract

To enhance the applicability of multiple solid waste road base materials in seasonally frozen soil areas and reduce the negative impact of red mud (RM) on the environment owing to its strong alkalinity, this paper utilizes untreated bayer method RM, fly ash (FA), and phosphogypsum (PG) as raw materials for preparing the road base materials. The mechanical properties, leaching characteristics, and Freeze-thaw (F-T) resistance of the materials from different solid waste systems were investigated through F-T cycle tests, unconfined compressive strength (UCS) tests, and leaching tests. The hydration, sodium solidification, and F-T deterioration mechanisms were revealed using an X-ray diffractometer and a scanning electron microscope. Results indicated that when the mix ratio of RM: FA: PG: cement was 64:28:2:6 (RFP2), the specimen exhibited the best F-T resistance. After 10 F-T cycles, the compressive strength retention rate (BDR) of the specimen was 91.43 %, and the Na⁺ leaching concentration was 390 mg/L, which still met the Chinese standard. The main hydration products of the material include C-S-H gel and ettringite crystals. These crystals and gels are intertwined and connected to form a dense mesh structure, which improves the material's F-T resistance and sodium solidification effect. The F-T cycle results in the expansion of cracks within the material, which leads to the destruction of the adhesion of the cementitious products, thus causing a deterioration of the strength of the specimen and the reduction of the sodium solidification effect.