Modulation-enabled healable and stretchable shape-memory polymer composites for digital light processing 4D printing

IF 10.3 1区工程技术 Q1 ENGINEERING, MANUFACTURING

Additive manufacturing Pub Date : 2025-02-12 DOI:10.1016/j.addma.2025.104699

Wei Huang , Wenqing Chen , Vikramjeet Singh , Jianhui Zhang , Yu Wang , Mohammed Alabdullatif , Eral Bele , Gary J. Lye , Helen C. Hailes , Manish K. Tiwari

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引用次数: 0

Abstract

4D printing provides viable pathways for 3D-printed objects that require morphological, time-dependent adaptations. Among various 4D printing materials, shape-memory polymers (SMPs) are one of the most extensively utilized morphing materials. However, most existing SMPs in 4D printing systems suffer from irreparability and low stretchability due to abundant covalently cross-linked networks. Also, their shape-programming steps typically involve stringent temperature requirements (≥90 ºC) and lack strategies for remote controllability, significantly restricting their applicability. Herein, we report a novel thermoplastic polymer system with self-healing and highly stretchable shape-memory capabilities for digital light processing (DLP)-based 4D printing. This system was attained through the integration of two distinct compositions: a polymer-based framework that acts as the reinforcing phase; and an elastic lubricant featuring hydrogen bonds that facilitates self-healing, high stretchability, and enhanced shape recovery. Additionally, light-responsive capabilities were shown to be effectively achieved by introducing a novel cross-linker functionalized with biomass lignin. The rationally selected safer set of ingredients ensures that our printed shape-memory polymer composites (SMPCs) are biocompatible. We further demonstrate their potential applications in aerospace and healthcare. This work provides a foundation for the design and facilitation of intelligent materials, showcasing excellent properties across multiple fields.

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来源期刊

Additive manufacturing Materials Science-General Materials Science

CiteScore

19.80

自引率

12.70%

发文量

648

审稿时长

35 days

期刊介绍： Additive Manufacturing stands as a peer-reviewed journal dedicated to delivering high-quality research papers and reviews in the field of additive manufacturing, serving both academia and industry leaders. The journal's objective is to recognize the innovative essence of additive manufacturing and its diverse applications, providing a comprehensive overview of current developments and future prospects. The transformative potential of additive manufacturing technologies in product design and manufacturing is poised to disrupt traditional approaches. In response to this paradigm shift, a distinctive and comprehensive publication outlet was essential. Additive Manufacturing fulfills this need, offering a platform for engineers, materials scientists, and practitioners across academia and various industries to document and share innovations in these evolving technologies.