Localized iodinated poly (Vinylidene Difluoride)-based solid-state electrolyte for enhanced dendrite-free lithium metal batteries

IF 5.5 3区工程技术 Q1 ENGINEERING, CHEMICAL

Journal of the Taiwan Institute of Chemical Engineers Pub Date : 2025-02-15 DOI:10.1016/j.jtice.2025.106014

Tong Wu, Guodong Chen, Ying Zhu, Xingjie Chen, Yilin Zhu, Chunyan Lai

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Abstract

Background

Addressing the challenges of solid-state batteries in the new energy sector requires a focus on interface issues. The interface between the solid electrolyte and the lithium metal anode is crucial, as it significantly influences battery performance.

Methods

Iodine-introduced poly (vinylidene fluoride) (PVDF) solid electrolytes are synthesized by solution casting method. The electrolyte is found to form a stable LiI-containing and LiF-rich interface with the lithium metal anode by sputtering XPS.

Significant findings

The acquired electrolytes show outstanding lithium-ion conductivity (7.9 × 10⁻⁴ S cm⁻¹) and migration number (0.42). The Li || Li batteries with the proposed electrolyte can cycle stably for 1000 h at a current density of 0.1 mA cm⁻², the LFP || Li batteries maintain up to 97.2 % capacity retention at 0.5C after 1000 cycles, and 98.7 % capacity retention at 1C after 300 cycles. A pouch cell with the solid polymer electrolyte is able to undergo stably for >200 cycles at 0.5C.

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来源期刊

Journal of the Taiwan Institute of Chemical Engineers 工程技术-工程：化工

CiteScore

9.10

自引率

14.00%

发文量

362

审稿时长

35 days

期刊介绍： Journal of the Taiwan Institute of Chemical Engineers (formerly known as Journal of the Chinese Institute of Chemical Engineers) publishes original works, from fundamental principles to practical applications, in the broad field of chemical engineering with special focus on three aspects: Chemical and Biomolecular Science and Technology, Energy and Environmental Science and Technology, and Materials Science and Technology. Authors should choose for their manuscript an appropriate aspect section and a few related classifications when submitting to the journal online.