{"title":"Isopropanol Modified Hydrocarbon-Based Polymer: Toward an Environmentally Friendly Large-Deformation Soft Actuator.","authors":"Yifan Li, Suqian Ma, Zirui Liu, Hao Zhang, Hui Xu, Yunhong Liang","doi":"10.1021/acs.nanolett.4c05430","DOIUrl":null,"url":null,"abstract":"<p><p>Ionic polymer-metal composites (IPMCs) with deformability are proposed as promising candidates for artificial muscles. However, the deficiencies of their most commonly used perfluoro polymer (Nafion) substrate cause non-negligible restrictions on its development. In this study, a novel environmentally friendly hydrocarbon-based IPMC is fabricated as an alternative to Nafion-based IPMC and successfully exhibits superior electrochemical characteristics (strip resistance reduced by 46% and capacitance increased 13-fold) and deformation performance (tip displacement of 41 mm at 3 V). Given its merits of fluorine-free, low cost (1/20 of Nafion), and no significant back relaxation, the hydrocarbon-based polymer is anticipated to be a possible solution to overcome the inherent drawbacks of perfluorinated substrates. Additionally, a series of multiform ultralow voltage (≤2.5 V) biomimetic flexible grippers are first designed using hydrocarbon-based IPMCs and show potential functionalities for capturing, orientating, and ejecting in fields such as biomimetic robotics, narrow-space engineering tasks, and design of miniature gripping devices.</p>","PeriodicalId":53,"journal":{"name":"Nano Letters","volume":" ","pages":""},"PeriodicalIF":9.6000,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nano Letters","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1021/acs.nanolett.4c05430","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Ionic polymer-metal composites (IPMCs) with deformability are proposed as promising candidates for artificial muscles. However, the deficiencies of their most commonly used perfluoro polymer (Nafion) substrate cause non-negligible restrictions on its development. In this study, a novel environmentally friendly hydrocarbon-based IPMC is fabricated as an alternative to Nafion-based IPMC and successfully exhibits superior electrochemical characteristics (strip resistance reduced by 46% and capacitance increased 13-fold) and deformation performance (tip displacement of 41 mm at 3 V). Given its merits of fluorine-free, low cost (1/20 of Nafion), and no significant back relaxation, the hydrocarbon-based polymer is anticipated to be a possible solution to overcome the inherent drawbacks of perfluorinated substrates. Additionally, a series of multiform ultralow voltage (≤2.5 V) biomimetic flexible grippers are first designed using hydrocarbon-based IPMCs and show potential functionalities for capturing, orientating, and ejecting in fields such as biomimetic robotics, narrow-space engineering tasks, and design of miniature gripping devices.
期刊介绍:
Nano Letters serves as a dynamic platform for promptly disseminating original results in fundamental, applied, and emerging research across all facets of nanoscience and nanotechnology. A pivotal criterion for inclusion within Nano Letters is the convergence of at least two different areas or disciplines, ensuring a rich interdisciplinary scope. The journal is dedicated to fostering exploration in diverse areas, including:
- Experimental and theoretical findings on physical, chemical, and biological phenomena at the nanoscale
- Synthesis, characterization, and processing of organic, inorganic, polymer, and hybrid nanomaterials through physical, chemical, and biological methodologies
- Modeling and simulation of synthetic, assembly, and interaction processes
- Realization of integrated nanostructures and nano-engineered devices exhibiting advanced performance
- Applications of nanoscale materials in living and environmental systems
Nano Letters is committed to advancing and showcasing groundbreaking research that intersects various domains, fostering innovation and collaboration in the ever-evolving field of nanoscience and nanotechnology.