Influence of Y2O3 Nano-Dispersoids on the Characteristics of AlCoCrFeNi2.1-Reinforced Tungsten Alloys via Mechanical Alloying and Low-Temperature Sintering.

Abstract

This study investigates the effects of nano-oxide dispersoids on microstructural evolution, phase formation, and mechanical properties of W-Mo-Ti alloys reinforced with AlCoCrFeNi_2.1 during mechanical alloying. An EBSD/EDS analysis confirmed the formation of different phases, including the tungsten matrix, FCC reinforcement phase, Al₂O₃, and (Al,Cr) oxide. Y₂O₃ particles played a crucial role in refining the microstructure, promoting a uniform dispersion of the reinforcement phase and oxide particles in the tungsten model alloys. Mechanical testing demonstrates that the Y₂O₃-containing alloy exhibits improved hardness with prolonged milling, attributed to the refinement in the microstructure. In contrast, the Y₂O₃-free alloy shows reduced hardness due to the agglomeration of reinforcement phases surrounded by an (Al,Cr) oxide layer. The model tungsten alloys exhibit brittle behavior in compression tests, which can be attributed to the presence of (Al,Cr) oxide layers weakening the interfacial bonding and limiting plastic deformation.