Recycled PET Packaging Materials of Improved Toughness— Importance of Devitrification of the Rigid Amorphous Fraction

IF 4.2 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Ferenc Ronkay, Dániel Gere, Emese Slezák, Edina Szabó, György Marosi, Katalin Bocz
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Abstract

Degradation, a common problem faced during the processing of recycled poly(ethylene terephthalate) (PET), leads to significant embrittlement of the products, as a result of which the material loses its applicability. Increased crystallization rate of the short chains of recycled PET and obstructed mobility of the amorphous phase are the main causes of enhanced brittleness. In this research, a straightforward method is proposed for improving the toughness of recycled PET products, namely the devitrification of the rigid amorphous phase by thermal annealing, which results in enhanced molecular mobility in the amorphous fraction, thereby promoting ductile deformation. The effects of thermal annealing conditions are comprehensively evaluated on the microstructure and macroscopic properties, i.e., impact resistance, of recycled PET films. The perforation energy value of the recycled PET film is found to increase to its threefold, reaching a value higher than 18 J mm−1, as a result of 10 s thermal treatment at 120 °C. Differential scanning calorimetry, dynamic mechanical analyses, and thermally stimulated depolarization current measurements provide evidence for the devitrification of the rigid amorphous fraction under these conditions, which is the key to efficient enhancement in toughness.

Abstract Image

提高韧性的再生PET包装材料-刚性非晶部分脱硝的重要性
降解是再生聚对苯二甲酸乙二醇酯(PET)加工过程中面临的一个普遍问题,它会导致产品出现明显的脆化,从而使材料失去适用性。再生PET短链晶化速度加快和非晶相迁移受阻是脆性增强的主要原因。本研究提出了一种提高再生PET制品韧性的直接方法,即通过热退火使刚性非晶相脱硝,使非晶部分的分子迁移率增强,从而促进韧性变形。综合评价了热处理条件对再生PET薄膜微观结构和宏观性能(即抗冲击性能)的影响。经120℃热处理10 s后,PET膜的穿孔能值增加了3倍,达到18 J mm−1以上。差示扫描量热法、动态力学分析和热激退极化电流测量为刚性非晶部分在这些条件下的反玻璃化提供了证据,这是有效增强韧性的关键。
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来源期刊
Macromolecular Materials and Engineering
Macromolecular Materials and Engineering 工程技术-材料科学:综合
CiteScore
7.30
自引率
5.10%
发文量
328
审稿时长
1.6 months
期刊介绍: Macromolecular Materials and Engineering is the high-quality polymer science journal dedicated to the design, modification, characterization, processing and application of advanced polymeric materials, including membranes, sensors, sustainability, composites, fibers, foams, 3D printing, actuators as well as energy and electronic applications. Macromolecular Materials and Engineering is among the top journals publishing original research in polymer science. The journal presents strictly peer-reviewed Research Articles, Reviews, Perspectives and Comments. ISSN: 1438-7492 (print). 1439-2054 (online). Readership:Polymer scientists, chemists, physicists, materials scientists, engineers Abstracting and Indexing Information: CAS: Chemical Abstracts Service (ACS) CCR Database (Clarivate Analytics) Chemical Abstracts Service/SciFinder (ACS) Chemistry Server Reaction Center (Clarivate Analytics) ChemWeb (ChemIndustry.com) Chimica Database (Elsevier) COMPENDEX (Elsevier) Current Contents: Physical, Chemical & Earth Sciences (Clarivate Analytics) Directory of Open Access Journals (DOAJ) INSPEC (IET) Journal Citation Reports/Science Edition (Clarivate Analytics) Materials Science & Engineering Database (ProQuest) PASCAL Database (INIST/CNRS) Polymer Library (iSmithers RAPRA) Reaction Citation Index (Clarivate Analytics) Science Citation Index (Clarivate Analytics) Science Citation Index Expanded (Clarivate Analytics) SciTech Premium Collection (ProQuest) SCOPUS (Elsevier) Technology Collection (ProQuest) Web of Science (Clarivate Analytics)
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