{"title":"Method for the β-selective radical C(sp3)–H functionalization of silanes","authors":"","doi":"10.1038/s44160-024-00675-6","DOIUrl":null,"url":null,"abstract":"Site-selective C–H bond functionalization of silanes is challenging because of the presence of multiple C–H bonds. Now, a photocatalytic method for the radical β-C(sp3)–H functionalization of silanes using the β-silicon effect is developed, enabling the aminoalkylation, alkylation and arylation of simple silanes to prepare more complex organosilicon compounds.","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"4 2","pages":"152-153"},"PeriodicalIF":0.0000,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nature synthesis","FirstCategoryId":"1085","ListUrlMain":"https://www.nature.com/articles/s44160-024-00675-6","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"0","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Site-selective C–H bond functionalization of silanes is challenging because of the presence of multiple C–H bonds. Now, a photocatalytic method for the radical β-C(sp3)–H functionalization of silanes using the β-silicon effect is developed, enabling the aminoalkylation, alkylation and arylation of simple silanes to prepare more complex organosilicon compounds.
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