Comprehensive investigation of epoxy/graphene oxide/copper nanocomposites: experimental study and modeling-optimization of mechanical characteristics

IF 2.4 3区 化学 Q3 POLYMER SCIENCE
Mehran Mahouri, Vali Parvaneh, Ali Dadrasi, Ghobad Shafiei Sabet
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引用次数: 0

Abstract

In the pursuit of advanced materials, researchers have turned to nanocomposites as a means to enhance both electrical conductivity and mechanical properties. The integration of copper nanoparticles (CNP) and graphene oxide (GO) into epoxy resin opened new routes for optimizing material performance, bridging the gap between electrical functionality and mechanical strength. This work, systematically examined the electrical conductivity, mechanical features, and optimized the mechanical characteristics of epoxy resin reinforced with CNP and GO using a multi-objective optimization design based on the genetic algorithm. The epoxy-based nanocomposites were reinforced up to 0.625 wt% of either GO or CNP and 1.25 wt% GO/CNP hybrid filler. Experimental results showed that the electrical conductivity increased in all nanocomposites by addition of fillers. Furthermore, the mechanical results indicated that tensile and flexural strength improved up to 47.54% and 26.83% in Epoxy/GO/CNP hybrid nanocomposite compared to the neat epoxy resin, respectively. Also, the optimum values were 41.62 MPa for tensile strength in 0.262 wt% GO and 0.018 wt% CNP, and 67.22 GPa for flexural strength in 0.344 wt% GO and 0.625 wt% CNP. Effective mechanisms of fillers have been analyzed by scanning electron microscopy and observed that agglomeration was dominant. These findings hold promise for advancing our understanding of nanocomposite behavior, particularly in the context of mechanical strength and electrical conductivity.

Graphical abstract

环氧/氧化石墨烯/铜纳米复合材料的综合研究:力学特性的实验研究和建模优化
在追求先进材料的过程中,研究人员已经将纳米复合材料作为提高导电性和机械性能的一种手段。将铜纳米颗粒(CNP)和氧化石墨烯(GO)集成到环氧树脂中,为优化材料性能开辟了新的途径,弥合了电气功能和机械强度之间的差距。本文采用基于遗传算法的多目标优化设计,系统考察了CNP和氧化石墨烯增强环氧树脂的电导率、力学特性,并对环氧树脂的力学特性进行了优化。环氧基纳米复合材料的氧化石墨烯或CNP含量为0.625 wt%,氧化石墨烯/CNP混杂填料含量为1.25 wt%。实验结果表明,填料的加入提高了纳米复合材料的导电性。力学结果表明,与纯环氧树脂相比,环氧树脂/氧化石墨烯/CNP杂化纳米复合材料的拉伸强度和弯曲强度分别提高了47.54%和26.83%。此外,在0.262 wt%氧化石墨烯和0.018 wt% CNP中,拉伸强度的最佳值为41.62 MPa,在0.344 wt%氧化石墨烯和0.625 wt% CNP中,弯曲强度的最佳值为67.22 GPa。通过扫描电镜分析了填料的作用机理,发现以团聚为主。这些发现有望促进我们对纳米复合材料行为的理解,特别是在机械强度和导电性方面。图形抽象
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来源期刊
Iranian Polymer Journal
Iranian Polymer Journal 化学-高分子科学
CiteScore
4.90
自引率
9.70%
发文量
107
审稿时长
2.8 months
期刊介绍: Iranian Polymer Journal, a monthly peer-reviewed international journal, provides a continuous forum for the dissemination of the original research and latest advances made in science and technology of polymers, covering diverse areas of polymer synthesis, characterization, polymer physics, rubber, plastics and composites, processing and engineering, biopolymers, drug delivery systems and natural polymers to meet specific applications. Also contributions from nano-related fields are regarded especially important for its versatility in modern scientific development.
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