Characterization of linear quadrupoles operated with amplitude-asymmetric sinusoidal waveforms.

IF 1.1 4区 化学 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL
Alexander I Ivanov, Alexey A Sysoev, Andrew N Konenkov, Nikolai V Konenkov
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引用次数: 0

Abstract

The stability regions formed by the asymmetric sinusoidal shape of the periodic supply potential of the quadrupole mass filter are calculated, with the signal duty cycle d=0.5. Two cases are considered, when A1<A2 and A1>A2, where A1 and A2 are the amplitudes of the positive and negative parts of the sinusoid. Stability islands are revealed, where the QMF operation is possible by changing amplitude A2 without DC potential. For the values A1=1 and A2=0.8, the mass selected instability mode with a resolution of about 7000 is found. In this island, the potential well depth reaches its maximum along the Y coordinate. At the amplitudes A1=1 and A2=1.8-2.0, stability regions are formed, the operation in which allows reaching R0.5=2000. The results of the transmission and excitation contours modeling confirm the validity of the method for calculating the stability diagrams of a linear quadrupole with asymmetric sinusoidal waveform.

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来源期刊
CiteScore
2.40
自引率
7.70%
发文量
16
审稿时长
>12 weeks
期刊介绍: JMS - European Journal of Mass Spectrometry, is a peer-reviewed journal, devoted to the publication of innovative research in mass spectrometry. Articles in the journal come from proteomics, metabolomics, petroleomics and other areas developing under the umbrella of the “omic revolution”.
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