Alexander I Ivanov, Alexey A Sysoev, Andrew N Konenkov, Nikolai V Konenkov
{"title":"Characterization of linear quadrupoles operated with amplitude-asymmetric sinusoidal waveforms.","authors":"Alexander I Ivanov, Alexey A Sysoev, Andrew N Konenkov, Nikolai V Konenkov","doi":"10.1177/14690667251315048","DOIUrl":null,"url":null,"abstract":"<p><p>The stability regions formed by the asymmetric sinusoidal shape of the periodic supply potential of the quadrupole mass filter are calculated, with the signal duty cycle <math><mi>d</mi><mo>=</mo><mn>0.5</mn></math>. Two cases are considered, when <math><msub><mi>A</mi><mn>1</mn></msub><mo><</mo><mspace></mspace><msub><mi>A</mi><mn>2</mn></msub></math> and <math><msub><mi>A</mi><mn>1</mn></msub><mo>></mo><msub><mi>A</mi><mn>2</mn></msub></math>, where <math><msub><mi>A</mi><mn>1</mn></msub></math> and <math><msub><mi>A</mi><mn>2</mn></msub></math> are the amplitudes of the positive and negative parts of the sinusoid. Stability islands are revealed, where the QMF operation is possible by changing amplitude <math><msub><mi>A</mi><mn>2</mn></msub></math> without DC potential. For the values <math><msub><mi>A</mi><mn>1</mn></msub><mo>=</mo><mn>1</mn></math> and <math><msub><mi>A</mi><mn>2</mn></msub><mo>=</mo><mn>0.8</mn></math>, the mass selected instability mode with a resolution of about 7000 is found. In this island, the potential well depth reaches its maximum along the <i>Y</i> coordinate. At the amplitudes <math><msub><mi>A</mi><mn>1</mn></msub><mo>=</mo><mn>1</mn></math> and <math><msub><mi>A</mi><mn>2</mn></msub><mo>=</mo><mn>1.8</mn><mo>-</mo><mn>2.0</mn></math>, stability regions are formed, the operation in which allows reaching <math><msub><mi>R</mi><mrow><mn>0.5</mn></mrow></msub><mo>=</mo><mn>2000</mn></math>. The results of the transmission and excitation contours modeling confirm the validity of the method for calculating the stability diagrams of a linear quadrupole with asymmetric sinusoidal waveform.</p>","PeriodicalId":12007,"journal":{"name":"European Journal of Mass Spectrometry","volume":" ","pages":"14690667251315048"},"PeriodicalIF":1.1000,"publicationDate":"2025-02-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Mass Spectrometry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1177/14690667251315048","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, ATOMIC, MOLECULAR & CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The stability regions formed by the asymmetric sinusoidal shape of the periodic supply potential of the quadrupole mass filter are calculated, with the signal duty cycle . Two cases are considered, when and , where and are the amplitudes of the positive and negative parts of the sinusoid. Stability islands are revealed, where the QMF operation is possible by changing amplitude without DC potential. For the values and , the mass selected instability mode with a resolution of about 7000 is found. In this island, the potential well depth reaches its maximum along the Y coordinate. At the amplitudes and , stability regions are formed, the operation in which allows reaching . The results of the transmission and excitation contours modeling confirm the validity of the method for calculating the stability diagrams of a linear quadrupole with asymmetric sinusoidal waveform.
期刊介绍:
JMS - European Journal of Mass Spectrometry, is a peer-reviewed journal, devoted to the publication of innovative research in mass spectrometry. Articles in the journal come from proteomics, metabolomics, petroleomics and other areas developing under the umbrella of the “omic revolution”.