Iron phthalocyanine-catalyzed aerobic oxidation of olefins enabled by metal-hydride hydrogen atom transfer

IF 1.5 4区化学 Q3 CHEMISTRY, ORGANIC

Tetrahedron Letters Pub Date : 2025-02-04 DOI:10.1016/j.tetlet.2025.155492

Yunfei Liu, Kaikai Qiao, Junfeng Yang, Wenfeng Jiang, Rong Zhang, Lei Shi

引用次数: 0

Abstract

We have established an MHAT-driven oxidation process to transform olefins into ketones, using inexpensive and readily available iron phthalocyanine as a catalyst. Various acetophenone derivatives were obtained with a low catalyst loading of only 0.5 mol% at room temperature and in an air atmosphere. This methodology has good compatibility with a wide range of differently substituted functional groups.

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来源期刊

Tetrahedron Letters 化学-有机化学

CiteScore

3.50

自引率

5.60%

发文量

521

审稿时长

28 days

期刊介绍： Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.